Methyl tetrahydrofurfuryl ether

Base Information

• Chemical Name: Methyl tetrahydrofurfuryl ether
• CAS No.: 19354-27-9
• Molecular Formula: C6H12O2
• Molecular Weight: 116.16
• Hs Code.: 29321900
• European Community (EC) Number: 242-986-7
• NSC Number: 93893
• DSSTox Substance ID: DTXSID80871290
• Nikkaji Number: J150.089I
• Mol file: 19354-27-9.mol

Synonyms:Methyl tetrahydrofurfuryl ether;19354-27-9;2-(Methoxymethyl)tetrahydrofuran;2-(methoxymethyl)oxolane;Furan, tetrahydro-2-(methoxymethyl)-;METHYLTETRAHYDROFURFURYLETHER;EINECS 242-986-7;AI3-30795;2-methoxymethyl-tetrahydrofuran;2-(Methoxymethyl)-tetrahydrofuran;SCHEMBL246371;Tetrahydrofurfuryl methyl ether;SCHEMBL13088434;DTXSID80871290;NSC93893;NSC 93893;NSC-93893;AKOS015912712;CS-0376672;FT-0637836;J-640066;J-800068

Chemical Property of Methyl tetrahydrofurfuryl ether

Chemical Property:

• Vapor Pressure: 7.79mmHg at 25°C
• Refractive Index: 1.425-1.427
• Boiling Point: 140 °C at 760 mmHg
• Flash Point: 33.3 °C
• PSA: 18.46000
• Density: 0.939 g/cm³
• LogP: 0.81180
• Storage Temp.: Flammables area
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 116.083729621
• Heavy Atom Count: 8
• Complexity: 63.5

Purity/Quality:

97 % ^*data from raw suppliers

METHYL TETRAHYDROFURFURYL ETHER 97.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:Flammable.
• Hazard Codes: R10:Flammable.
• Statements: 10
• Safety Statements: 16-33-29

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCC1CCCO1

Technology Process of Methyl tetrahydrofurfuryl ether

There total 15 articles about Methyl tetrahydrofurfuryl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

Tetrahydrofurfuryl alcohol (97-99-4) + carbonic acid dimethyl ester (616-38-6) → methyl tetrahydrofurfuryl ether (19354-27-9)

Guidance literature:

With hydrotalcite 30; at 260 ℃; for 6h; under 7500.75 Torr;

DOI:10.1002/cssc.201601765

Reference yield: 75.0%

methanol (67-56-1) + 2-(phenylselanylmethyl)oxolane (65539-72-2) → methyl tetrahydrofurfuryl ether (19354-27-9)

Guidance literature:

With naphthalene-1,4-dicarbonitrile; for 8h; Ambient temperature; Irradiation;

DOI:10.1021/jo00103a031

Reference yield: 70.0%

→ methyl tetrahydrofurfuryl ether (19354-27-9)

Guidance literature:

upstream raw materials:

Tetrahydrofurfuryl alcohol

dimethyl sulfate

methyl iodide

methanol

Downstream raw materials:

tetrahydrofurfuryl acetate

(tetrahydrofuran-2-yl)methyl benzoate

Refernces

• 1、 Kirner. "-". . p. 3251,3252. Retrieved 1930.
• 2、 Cattelan, Lisa,Perosa, Alvise,Riello, Piero,Maschmeyer, Thomas,Selva, Maurizio. "Continuous-Flow O-Alkylation of Biobased Derivatives with Dialkyl Carbonates in the Presence of Magnesium–Aluminium Hydrotalcites as Catalyst Precursors". . p. 1571 - 1583. Retrieved 2017/04/14.
• 3、 Lee, Jechan,Kim, Yong Tae,Huber, George W.. "Aqueous-phase hydrogenation and hydrodeoxygenation of biomass-derived oxygenates with bimetallic catalysts". supporting information. p. 708 - 718. Retrieved 2014/02/14.