9-Phenylxanthylium perchlorate

Base Information

• Chemical Name: 9-Phenylxanthylium perchlorate
• CAS No.: 6631-16-9
• Molecular Formula: C₁₉H₁₃O*ClO₄
• Molecular Weight: 356.762
• NSC Number: 55858
• Mol file: 6631-16-9.mol

Synonyms:6631-16-9;NSC55858;9-phenylxanthylium perchlorate;NSC-55858

Chemical Property of 9-Phenylxanthylium perchlorate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 87.41000
• Density: g/cm³
• LogP: 5.74840
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 356.0451512
• Heavy Atom Count: 25
• Complexity: 394

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC=CC3=[O+]C4=CC=CC=C42.[O-]Cl(=O)(=O)=O

Technology Process of 9-Phenylxanthylium perchlorate

There total 10 articles about 9-Phenylxanthylium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

9-phenyl-9H-xanthen-9-ol (596-38-3) → 9?phenylxanthen?9?ylium perchlorate (6631-16-9)

Guidance literature:

With perchloric acid; for 5h;

DOI:10.1002/poc.3975

Reference yield: 67.0%

bromobenzene (108-86-1,52753-63-6) + xanth-9-one (90-47-1) → 9?phenylxanthen?9?ylium perchlorate (6631-16-9)

Guidance literature:

bromobenzene; With iodine; magnesium; In tetrahydrofuran; Inert atmosphere; Reflux;

xanth-9-one; In tetrahydrofuran; at 0 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tet.2020.131222

Reference yield:

(9-phenyl-xanthen-9-ylmercapto)-acetic acid (860743-67-5) → 9?phenylxanthen?9?ylium perchlorate (6631-16-9)

Guidance literature:

With perchloric acid;

DOI:10.1021/ja01304a032

upstream raw materials:

(9-phenyl-xanthen-9-ylmercapto)-acetic acid

perchloric acid

9-(2,2-diphenyl-vinyl)-9-phenyl-xanthene

bromine

Downstream raw materials:

dimethyl-(9-phenyl-xanthen-9-yl)-amine

9-phenyl-9-(phenylthio)-xanthene

9-phenyl-9H-xanthene

Refernces

• 1、 Zoric, Marija R.,Singh, Varun,Zeller, Matthias,Glusac, Ksenija D.. "Conformational analysis of diols: Role of the linker on the relative orientation of hydroxyl groups". . . Retrieved 2019.
• 2、 Barton, Benita,Jooste, Daniel V.,Hosten, Eric C.. "Synthesis and assessment of compounds trans-N,N′-bis(9-phenyl-9-xanthenyl)cyclohexane-1,4-diamine and trans-N,N′-bis(9-phenyl-9-thioxanthenyl)cyclohexane-1,4-diamine as hosts for potential xylene and ethylbenzene guests". . p. 333 - 346. Retrieved 2019/03/23.