silyl formate

Base Information

• Chemical Name: silyl formate
• CAS No.: 6876-42-2
• Molecular Formula: CH4O2Si
• Molecular Weight: 76.1271
• Mol file: 6876-42-2.mol

Synonyms:

Chemical Property of silyl formate

Chemical Property:

• Vapor Pressure: 344mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silyl formate

There total 6 articles about silyl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

tributyltin formate (5847-51-8) → formoxysilane (6876-42-2)

Guidance literature:

With silyl bromide; for 0.0166667h; Ambient temperature;

DOI:10.1007/BF00938727

Reference yield:

silyl bromide (14791-57-2) + tributyltin formate (5847-51-8) → formoxysilane (6876-42-2) + tributyltin bromide (1461-23-0)

Guidance literature:

room temp.;

DOI:10.1007/BF00938727

Reference yield:

carbon dioxide (124-38-9,18923-20-1) → methoxysilane (2171-96-2) + formoxysilane (6876-42-2) + bis(silyl)acetal

Guidance literature:

With phenylsilane; potassium tert-butylate; [Co(2,6-bis((1,3-diisopropyl-1,3,2-diazaphospholidin)N-methylamino)-4-phenyltriazine)Cl₂]; In neat liquid; at 80 ℃; for 6h; Solvent; Catalytic behavior; Schlenk technique;

DOI:10.1002/ange.202004463

upstream raw materials:

tributyltin formate

diformatosilane

silyl bromide

carbon dioxide

Refernces

• 1、 Chatterjee, Basujit,Cramer, Hanna H.,Leitner, Walter,Werlé, Christophe,Weyhermüller, Thomas. "Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex". supporting information. p. 15674 - 15681. Retrieved 2020/06/08.
• 2、 Bett, William,Cradock, Stephen. "Preparation of Some Silyl Esters and Study of Their Vibration Spectra in Gas and Condensed Phases". . p. 193 - 198. Retrieved 2007/10/02.