n-Tetratriacontane

Base Information

• Chemical Name: n-Tetratriacontane
• CAS No.: 14167-59-0
• Molecular Formula: C34H70
• Molecular Weight: 478.93
• European Community (EC) Number: 238-013-0
• NSC Number: 2998
• UNII: 94UA0738YX
• DSSTox Substance ID: DTXSID7058622
• Nikkaji Number: J122.952D
• Wikidata: Q151145
• Metabolomics Workbench ID: 5282
• Mol file: 14167-59-0.mol

Synonyms:NSC 2998;n-Tetratriacontane

Chemical Property of n-Tetratriacontane

Chemical Property:

• Vapor Pressure: 5.36E-09mmHg at 25°C
• Melting Point: 72-75 °C(lit.)
• Boiling Point: 482.4°Cat760mmHg
• Flash Point: 345.3°C
• PSA: 0.00000
• Density: 0.812g/cm³
• LogP: 13.50940
• XLogP3: 18
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 31
• Exact Mass: 478.547752233
• Heavy Atom Count: 34
• Complexity: 288

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Saturated (>C11)
• Canonical SMILES: CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

Technology Process of n-Tetratriacontane

There total 17 articles about n-Tetratriacontane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.5%

stearic acid (57-11-4) → n-tetratriacontane (14167-59-0)

Guidance literature:

With sodium methylate; In methanol; at 40 - 60 ℃; Product distribution / selectivity; Electrolysis;

Reference yield: 34.0%

stearic acid (57-11-4) → hepatdecane (629-78-7) + heptadec-1-ene (6765-39-5) + n-tetratriacontane (14167-59-0)

Guidance literature:

With potassium methanolate; In methanol; at 40 - 45 ℃; electrolysis: anode: platinum foil; current source: galvanostat; current density 200 mA cm^-2; current consumption: 0.58 F mol^-1; cell voltage 60-110 V;

DOI:10.3891/acta.chem.scand.52-0672

Reference yield:

decane (124-18-5) → octane (111-65-9) + nonane (111-84-2) + n-Undecane (1120-21-4) + dodecane (112-40-3) + hexane (110-54-3) + n-heptane (142-82-5) + tritriacontane (630-05-7) + n-tetratriacontane (14167-59-0) + n-butane (106-97-8,9003-29-6,9021-92-5) + pentane (109-66-0,8031-35-4,9078-70-0)

Guidance literature:

With C₃₂H₆₀IrO₃P₃; Re₂O₇/Al₂O₃; 1,3,5-trimethyl-benzene; at 175 ℃; for 168h; Inert atmosphere;

DOI:10.1002/adsc.200900539

upstream raw materials:

1-iodo-tetratriacontane

1-iodoheptadecane

potassium stearate

acetic acid

Downstream raw materials:

carbon dioxide

Refernces

• 1、 Francis,Wood. "-". . p. 1420. Retrieved 1926.
• 2、 -. "WAX COMPOSITIONS COMPRISING LINEAR OLEFIN DIMERS OR HODROGENATED VARIANTS THEREOF AND METHODS FOR PRODUCTION THEREOF". Paragraph 0142-0147; 150. . Retrieved 2021/09/17.
• 3、 -. "Long chain (C22-C50) polyunsaturated hydrocarbons, derivatives, synthesis and uses thereof". Page/Page column 18-19. . Retrieved 2009/09/08.