(3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE

Base Information

• Chemical Name: (3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE
• CAS No.: 429-60-7
• Deprecated CAS: 871118-65-9,1129493-98-6
• Molecular Formula: C6H13F3O3Si
• Molecular Weight: 218.248
• Hs Code.: 29319090
• European Community (EC) Number: 207-059-3
• DSSTox Substance ID: DTXSID2059984
• Nikkaji Number: J196.111J
• Mol file: 429-60-7.mol

Synonyms:(3,3,3-Trifluoropropyl)trimethoxysilane;1,1,1-Trifluoro-3-(trimethoxysilyl)propane;AP Silane 75;AY 43-013;FAS 3;FAS3 (silane);KBM 7103;LS 1090;Q 3-9030;T 2847;TSL 8262;Trimethoxy(3,3,3-trifluoropropyl)silane;XC 95-418;Z 6333;

Chemical Property of (3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE

Chemical Property:

• Appearance/Colour: Colorless clear liquid
• Vapor Pressure: 15.4mmHg at 25°C
• Refractive Index: n20/D 1.355
• Boiling Point: 124.406 °C at 760 mmHg
• Flash Point: 29.04 °C
• PSA: 27.69000
• Density: 1.098 g/cm³
• LogP: 1.81690
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 218.05860529
• Heavy Atom Count: 13
• Complexity: 138

Purity/Quality:

99%min ^*data from raw suppliers

(3,3,3-Trifluoropropyl)trimethoxysilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi, F
• Hazard Codes: Xi,F
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CO[Si](CCC(F)(F)F)(OC)OC
• Uses: (3,3,3-Trifluoropropyl)trimethoxysilane is used in the manufacture of defoaming agents, releasing agents, fluoro silicone resin and coating. It is used as a coupling agent for epoxy resin. Trimethoxy(3,3,3-trifluoropropyl)silane is commonly used in the synthesis of a variety of silsesquioxane based polymers. It is a precursor in the synthesis of macroporous gels for separation of oil and water. It can also be used in the synthesis of hydrophobic silica aerogel for the removal of uranium from aqueous solutions.

Technology Process of (3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE

There total 3 articles about (3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethoxysilane (2487-90-3) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → 3,3,3-trifluoropropyltrimethoxysilane (429-60-7)

Guidance literature:

With caesium carbonate; triethylamine; [Rh{(Z)-CF=CF(CF₃)}(PEt₃)3]; In hexane; at 20 ℃; for 20h;

DOI:10.1002/anie.200700711

Reference yield:

methanol (67-56-1) + 3,3,3-trifluoropropyltrichlorosilane (592-09-6) → 3,3,3-trifluoropropyltrimethoxysilane (429-60-7)

Guidance literature:

DOI:10.1021/ja01566a082

Reference yield:

tetramethylorthosilicate (681-84-5) + 3,3,3-trifluoropropyl magnesium chloride (461-21-2) → 3,3,3-trifluoropropyltrimethoxysilane (429-60-7)

Guidance literature:

DOI:10.1021/ja01610a066

upstream raw materials:

methanol

3,3,3-trifluoropropyltrichlorosilane

tetramethylorthosilicate

3,3,3-trifluoropropyl magnesium chloride

Downstream raw materials:

3,3,3-trifluoropropyl-4-methylbenzene sulphonate

3,7-dimethyl-1-(3,3,3-trifluoro-propyl)-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane

1-(3,3,3-Trifluoropropyl)silatrane

3-Methyl-1-(3,3,3-trifluorpropyl)silatran

Refernces