trans-Carbonylchlorobis-(triphenylphosphino)-rhodium

Base Information

• Chemical Name: trans-Carbonylchlorobis-(triphenylphosphino)-rhodium
• CAS No.: 15318-33-9
• Molecular Formula: C₃₇H₃₀ClOP₂Rh
• Molecular Weight: 690.951
• Mol file: 15318-33-9.mol

Synonyms:Rhodium,carbonylchlorobis(triphenylphosphine)-, trans- (8CI);trans-Carbonylchlorobis(triphenylphosphine)rhodium;trans-Carbonylchlorobis(triphenylphosphine)rhodium(I)

Chemical Property of trans-Carbonylchlorobis-(triphenylphosphino)-rhodium

Chemical Property:

• PSA: 27.18000
• LogP: 6.92660

Purity/Quality:

99% ，98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-Carbonylchlorobis-(triphenylphosphino)-rhodium

There total 226 articles about trans-Carbonylchlorobis-(triphenylphosphino)-rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

5-hydroxymethyl-2-furfuraldehyde (67-47-0) + Wilkinson's catalyst (14694-95-2) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;

DOI:10.1021/om00113a029

Reference yield: 94.0%

Wilkinson's catalyst (14694-95-2) + sorbose (57-48-7,87-79-6,87-81-0,551-68-8,3615-39-2,3615-56-3,6035-50-3,7776-48-9,16354-64-6,17598-81-1,17598-82-2,23140-52-5,30237-26-4,65732-90-3,73952-10-0,73952-11-1,139686-85-4,18875-34-8) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + XYLITOL (87-99-0) + DL-1-deoxy-threitol (4144-94-9,4435-50-1,33818-52-9,41167-49-1,61913-75-5,61913-76-6,122920-28-9,138257-33-7)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, heating 6h;

DOI:10.1021/om00113a029

Reference yield: 92.0%

Wilkinson's catalyst (14694-95-2) + Cinnamoyl chloride (102-92-1,17082-09-6) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8)

Guidance literature:

With 1-hexene; In 1,2-dichloro-ethane; byproducts: styryltriphenyltriphosphonium chloride; evacuated and N2 added two times; dichloroethane addn.; evacuated untilboiled at room temp., and N2 added rapidly; cycle repeated; cooled to -78°C, tube sealed; heated 85°C 24 h; decane added; distd. the volatiles; residue recrysd. from dichloroethane;

DOI:10.1021/ja00396a031

upstream raw materials:

Wilkinson's catalyst

fructopyranose

crotonyl chloride

Cinnamoyl chloride

Downstream raw materials:

chloro(η-ethylene)bis(triphenylphosphine)rhodium(I)

Rh(CO)(P(C₆H₅)3)2Br₃

Tetramethyl ethylenetetracarboxylate

Rh(I)Br(CO)(PPh₃)2

Refernces

• 1、 Chen, Si,Manoury, Eric,Poli, Rinaldo. "Slow exchange of bidentate ligands between rhodium(I) complexes: Evidence of both neutral and anionic ligand exchange". . p. 5820 - 5826. Retrieved 2015/02/19.
• 2、 Choinopoulos, Ioannis,Papageorgiou, Ioannis,Coco, Silverio,Simandiras, Emmanuel,Koinis, Spyros. "Modification of Wilkinson's catalyst with triphenyl phosphite: Synthesis, structure, 31P NMR and DFT study of trans-[RhCl(P(OPh) 3)(PPh3)2]". . p. 255 - 261. Retrieved 2013/01/13.