Hydroperoxide, trichloromethyl

Base Information

• Chemical Name: Hydroperoxide, trichloromethyl
• CAS No.: 94089-33-5
• Molecular Formula: CHCl3O2
• Molecular Weight: 151.377
• Mol file: 94089-33-5.mol

Synonyms:

Chemical Property of Hydroperoxide, trichloromethyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hydroperoxide, trichloromethyl

There total 11 articles about Hydroperoxide, trichloromethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroform (67-66-3,8013-54-5) + oxygen (80937-33-3) → phosgene (75-44-5) + Trichlormethylhydroperoxid (94089-33-5)

Guidance literature:

In melt; other Radiation; radiation with 60Co-γ, 1/100 equimolar amt. of O2, molten ampoulle, at 22°C; identification by spectral photometer;

DOI:10.1021/ja01105a059

Reference yield:

trichloromethyl peroxyl (69884-58-8) + ascorbate (299-36-5) → Trichlormethylhydroperoxid (94089-33-5) + ascorbic acid radical anion (63983-50-6)

Guidance literature:

In water; isopropyl alcohol; Rate constant;

DOI:10.1021/j100347a045

Reference yield:

vitamin C (50-81-7,98966-42-8) + trichloromethyl peroxyl (69884-58-8) → Monodehydroascorbinsaeure-Radikal (10550-31-9,14599-22-5,34622-13-4,34622-14-5,299-36-5,138050-70-1,149097-58-5) + Trichlormethylhydroperoxid (94089-33-5)

Guidance literature:

In water; isopropyl alcohol; at 21 ℃; Rate constant; pH = 1, effect of the solvent ratio;

DOI:10.1021/j100359a025

upstream raw materials:

vitamin C

trichloromethyl peroxyl

N,N,N',N'-tetramethyl-para-phenylenediamine

4-(N,N-dimethylamino)phenol

Refernces

• 1、 Nahor, G. S.,Neta, P.,Alfassi, Z. B.. "Perfluorobutylperoxyl Radical as an Oxidant in Various Solvents". . p. 4419 - 4422. Retrieved 2007/10/02.