BORON SUBPHTHALOCYANINE CHLORIDE

Base Information

• Chemical Name: BORON SUBPHTHALOCYANINE CHLORIDE
• CAS No.: 36530-06-0
• Molecular Formula: C24H12BClN6
• Molecular Weight: 430.663
• Hs Code.: 3212900000
• Mol file: 36530-06-0.mol

Synonyms:BORON SUBPHTHALOCYANINE CHLORIDE;Boron subphthalocyanine chloride Dye content ~85 %

Chemical Property of BORON SUBPHTHALOCYANINE CHLORIDE

Chemical Property:

• Melting Point: >360 °C(lit.)
• PSA: 61.42000
• LogP: 5.28450
• Storage Temp.: Amber Vial, -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), Methanol (slightly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

Boron subphthalocyanine chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Boron Subphthalocyanine Chloride is an organic material used in photoelectric conversion organic layers used as semiconducting materials. Also used as a dye in luminescent materials.

Technology Process of BORON SUBPHTHALOCYANINE CHLORIDE

There total 4 articles about BORON SUBPHTHALOCYANINE CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

boron trichloride (10294-34-5) + phthalonitrile (91-15-6) → subphthalocyanine (36530-06-0)

Guidance literature:

In para-xylene; Glovebox; Reflux;

DOI:10.3390/molecules25112575

Reference yield: 75.0%

phthalonitrile (91-15-6) → subphthalocyanine (36530-06-0)

Guidance literature:

With boron trichloride; In para-xylene; for 0.5h; Reflux; Inert atmosphere;

DOI:10.1016/j.tet.2009.01.046

Reference yield: 30.0%

2-chloronaphthalene (91-58-7) + boron trichloride (10294-34-5) + phthalonitrile (91-15-6) → subphthalocyanine (36530-06-0)

Guidance literature:

(Ar); stirring at -78°C, heating at reflux temp. for 15 min.; product dissolved in sulfuric acid and precipitated with ice-water mixture;

DOI:10.1021/j100041a012

upstream raw materials:

phthalonitrile

thionyl chloride

bromo-[7,12:14,19-diimino-21,5-nitrilo-5H-tribenzo[c,h,m][1,6,11]triazacyclopentadecinato-(2)-κN22,κN23,κN24]-boron(III)

boron trichloride

Downstream raw materials:

(4-fluorophenoxy)boronsubphthalocyanine

(4-tert-butylphenoxy)boronsubphthalocyanine

phenoxysubphthalocyaninatoboron

B(subphthalocyanine)(ethynylphenyliodo)

Refernces

• 1、 Roy, Palas,Bressan, Giovanni,Gretton, Jacob,Cammidge, Andrew N.,Meech, Stephen R.. "Ultrafast Excimer Formation and Solvent Controlled Symmetry Breaking Charge Separation in the Excitonically Coupled Subphthalocyanine Dimer". . p. 10568 - 10572. Retrieved 2021.
• 2、 Tempesti, Tomas C.,Baumgartner, María T.. "Synthesis of phthalonitrile derivatives by photoinduced reactions. New unsymmetrical substituted zinc phthalocyanines". . p. 1088 - 1094. Retrieved 2015.
• 3、 Chauhan,Kumari, Pratibha. "Synthesis of unsymmetrical benzoporphyrazines in functional ionic liquids and formation of self-aggregates of zinc(II) pyridino[3,4]tribenzoporphyrazines in solutions". . p. 2518 - 2524. Retrieved 2009.
• 4、 Conradie, Jeanet,Swarts, Pieter J.. "Synthesis, spectroscopy, electrochemistry and DFT of electron-rich ferrocenylsubphthalocyanines". supporting information. . Retrieved 2020/07/02.