N-(2-BroMophenyl)-9H-carbazole

Base Information

• Chemical Name: N-(2-BroMophenyl)-9H-carbazole
• CAS No.: 902518-11-0
• Molecular Formula: C18H12BrN
• Molecular Weight: 322.204
• Hs Code.: 2933990090
• Mol file: 902518-11-0.mol

Synonyms:9-(2-bromophenyl)carbazole;

Chemical Property of N-(2-BroMophenyl)-9H-carbazole

Chemical Property:

• Melting Point: 93-94℃
• Boiling Point: 462.0±37.0 °C at 760 mmHg
• Flash Point: 233.2±26.5 °C
• PSA: 4.93000
• Density: 1.4±0.1 g/cm³
• LogP: 5.54620
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99.0% ^*data from raw suppliers

9-(2-Bromophenyl)-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-41
• Safety Statements: 26-39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 9-(2-Bromophenyl)-9H-carbazole is a useful reagent for organic synthesis.

Technology Process of N-(2-BroMophenyl)-9H-carbazole

There total 9 articles about N-(2-BroMophenyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

o-fluorobromobenzene (1072-85-1) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-(2-bromophenyl)-9H-carbazole (902518-11-0)

Guidance literature:

With caesium carbonate; In 1-methyl-pyrrolidin-2-one; at 160 ℃; for 16h;

Reference yield: 92.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + 2-bromophenylhydrazine (16732-66-4) → 9-(2-bromophenyl)-9H-carbazole (902518-11-0)

Guidance literature:

With manganese triacetate; sodium fluoride; In acetonitrile; at 30 ℃; for 4h;

Reference yield: 89.0%

→ 9-(2-bromophenyl)-9H-carbazole (902518-11-0)

Guidance literature:

With copper; potassium carbonate; In N,N-dimethyl acetamide; for 12h; Reflux;

upstream raw materials:

1-Bromo-2-iodobenzene

9H-carbazole

2,3-dibromobenzene

2-bromoaniline

Downstream raw materials:

9-(2-(diethylphosphino)phenyl)-9H-carbazole

9-(2-(di-tert-butylphosphino)phenyl)-9H-carbazole

9-(2-(di-iso-propylphosphino)phenyl)-9H-carbazole

9-(2-(diphenylphosphino)phenyl)-9H-carbazole

Refernces

• 1、 Chung, Won Jae,Konidena, Rajendra Kumar,Lee, Jun Yeob. "Enabling high efficiency and long lifetime of pure blue phosphorescent organic light emitting diodes by simple cyano modified carbazole-based host". . . Retrieved 2021.
• 2、 -. "Composition For Capping Layer of Organic Light Emitting Diode and Organic Light Emitting Diode Having The Same". Paragraph 0178-0182. . Retrieved 2021/02/16.
• 3、 -. "Hole transport type main body material, preparation method thereof and application of hole transport type main body material in preparation of organic electroluminescent device". Paragraph 0048-0053. . Retrieved 2021/08/07.