2-(acetoxymethyl)-5-oxotetrahy drofuran-3,4-diyl diacetate

Base Information

• Chemical Name: 2-(acetoxymethyl)-5-oxotetrahy drofuran-3,4-diyl diacetate
• CAS No.: 394739-29-8
• Molecular Formula: C₁₁H₁₄O₈
• Molecular Weight: 274.227
• Hs Code.: 2932190090
• Mol file: 394739-29-8.mol

Synonyms:2-(acetoxymethyl)-5-oxotetrahy drofuran-3,4-diyl diacetate

Chemical Property of 2-(acetoxymethyl)-5-oxotetrahy drofuran-3,4-diyl diacetate

Chemical Property:

• PSA: 105.20000
• LogP: -0.66170
• Storage Temp.: 2-8°C

Purity/Quality:

≥95% ^*data from raw suppliers

2-(acetoxymethyl)-5-oxotetrahydrofuran-3,4-diyldiacetate 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(acetoxymethyl)-5-oxotetrahy drofuran-3,4-diyl diacetate

There total 29 articles about 2-(acetoxymethyl)-5-oxotetrahy drofuran-3,4-diyl diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

acetic anhydride (108-24-7) + D-Ribono-1,4-lactone (5336-08-3) → 2,3,5-tri-O-acetyl-D-ribonic acid γ-lactone (41162-32-7,394739-29-8)

Guidance literature:

In neat (no solvent); at 25 ℃; for 3h; Temperature; Reagent/catalyst; Molecular sieve;

DOI:10.5935/0103-5053.20150037

Reference yield: 96.0%

acetic anhydride (108-24-7) + D-lyxono-1,4-lactone (15384-34-6) → tri-O-acetyl-D-lyxono-1,4-lactone (79580-61-3,394739-29-8)

Guidance literature:

With perchloric acid; for 0.5h; Ambient temperature;

Reference yield: 69.0%

acetic anhydride (108-24-7) + D-arabinono-1,4-lactone (2782-09-4) → 2,3,5-tri-O-acetyl-D-arabino-1,4-lactone (16751-37-4,394739-29-8)

Guidance literature:

With perchloric acid; for 0.5h; Ambient temperature;

upstream raw materials:

acetic anhydride

D-arabinono-1,4-lactone

2,3,4-tri-O-acetyl-1-deoxy-1-bromo-α-D-arabinopyranosyl cyanide

D-Glucose

Refernces

• 1、 Sebr?o, Damianni,Sá, Marcus M.,Nascimento, Maria Da Graa. "Regioselective acylation of d-ribono-1,4-lactone catalyzed by lipases". experimental part. p. 551 - 556. Retrieved 2012/01/13.
• 2、 Zhen, Zhi-Bin,Gao, Jian,Wu, Yikang. "A chiron approach to the total synthesis of (+)-aculeatin D". scheme or table. p. 7310 - 7316. Retrieved 2009/05/09.