Bismuth pentafluoride

Base Information

• Chemical Name: Bismuth pentafluoride
• CAS No.: 7787-62-4
• Molecular Formula: BiF5
• Molecular Weight: 303.972
• Hs Code.: 28261990
• European Community (EC) Number: 232-125-3
• DSSTox Substance ID: DTXSID10228490
• Wikipedia: Bismuth pentafluoride,Bismuth_pentafluoride
• Mol file: 7787-62-4.mol

Synonyms:Bismuth pentafluoride;7787-62-4;bismuth(V) fluoride;pentafluorobismuth;BiF5;UNII-BX273GFK98;EINECS 232-125-3;pentafluoridobismuth;Bi-F5;pentakis(fluoranyl)bismuth;[BiF5];CHEBI:30426;pentafluoro-lambda(5)-bismuthane;DTXSID10228490;MFCD00015967;AKOS015915834;FT-0623132;Bismuth(V) fluoride, 99.9% trace metals basis;A839257

Chemical Property of Bismuth pentafluoride

Chemical Property:

• Melting Point: 550°C (subl.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -14.98000
• Water Solubility.: violent reaction with H2O to form BiF3 and ozone [MER06]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 303.97241
• Heavy Atom Count: 6
• Complexity: 37.1

Purity/Quality:

98%min ^*data from raw suppliers

Bismuth(V) fluoride 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O,C
• Hazard Codes: O,C
• Statements: 8-34
• Safety Statements: 17-26-27-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: F[Bi](F)(F)(F)F

Technology Process of Bismuth pentafluoride

There total 14 articles about Bismuth pentafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bismuth(V) oxide + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + bismuth(III) oxide (1304-76-3) → bismuth(III) fluoride (7787-61-3) + bismuth pentafluoride (7787-62-4)

Guidance literature:

In water;

Reference yield:

BrF2 bismuth hexafluoride (36608-81-8) → bromine trifluoride (7787-71-5) + bismuth(III) fluoride (7787-61-3) + bismuth pentafluoride (7787-62-4) + bromine pentafluoride (177570-08-0,7789-30-2,676353-69-8)

Guidance literature:

In neat (no solvent); dry air atmosphere; heating (100-200°C, 4-6 K/min); TGA;

Reference yield:

bismuth (7440-69-9) + fluorine (7782-41-4) → bismuth pentafluoride (7787-62-4)

Guidance literature:

In neat (no solvent); flow reactor, 500°C; X-ray diffraction;

upstream raw materials:

hydrogen fluoride

bismuth(III) oxide

bismuth

nitrylfluoride

Downstream raw materials:

bromine trifluoride

silicon tetrafluoride

uranium hexafluoride

bismuth(III) fluoride

Refernces

• 1、 Bougon, Roland,Charpin, Pierrette,Christe, Karl O.,Isabey, Jacques,Lance, Monique,Nierlich, Martine,Vigner, Julien,Wilson, William W.. "Preparation and characterization of Ni(BiF6)2 and of the ternary adducts [Ni(CH3CN)6](BiF6)2 and [Ni(CH3CN)6](SbF6)2. Crystal structure of [Ni(CD3CN)6](SbF6)2". . p. 1389 - 1393. Retrieved 2008/10/08.