Platinum(4+) tetrachloride

Base Information

• Chemical Name: Platinum(4+) tetrachloride
• CAS No.: 13454-96-1
• Molecular Formula: PtCl4
• Molecular Weight: 336.892
• Hs Code.: 28439090
• UNII: W3YUG71TU2
• DSSTox Substance ID: DTXSID601014389
• Nikkaji Number: J43.968A
• Mol file: 13454-96-1.mol

Synonyms:platinum(4+) tetrachloride;DTXSID601014389;AKOS016010302;PLATINUM (IV) CHLORIDE [HSDB];PLATINUM TETRACHLORIDE [WHO-DD];A806795

Chemical Property of Platinum(4+) tetrachloride

Chemical Property:

• Appearance/Colour: brown/red crystals
• Melting Point: 370 °C
• PSA: 0.00000
• Density: 4.303 g/cm³
• LogP: 2.75550
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: 587g/l
• Water Solubility.: 587 g/L (25 ºC)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 336.837255
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Platinum(IV) chloride (99.9%-Pt) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 22-34-42/43
• Safety Statements: 26-27-36/37/39-45-24-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Pt+4]
• Uses: Platinum(IV) chloride is used as a catalyst and analytical reagent. Further, it is used in the production of semiconductor epitaxy and in electroplating process. It is involved in the preparation of platinum(II) chloride .

Technology Process of Platinum(4+) tetrachloride

There total 37 articles about Platinum(4+) tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ platinum(IV) chloride (13454-96-1)

Guidance literature:

Reference yield:

sulfuryl dichloride (7791-25-5) + platinum (7440-06-4) → platinum(IV) chloride (13454-96-1)

Guidance literature:

In neat (no solvent); heating for some days to 150°C;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + platinum (7440-06-4) → platinum(IV) chloride (13454-96-1)

Guidance literature:

With tris-(2-chloro-ethyl)-amine; In not given; byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;;

DOI:10.1021/ja02205a006

upstream raw materials:

sulfuryl dichloride

platinum

hydrogenchloride

chlorine

Downstream raw materials:

carbon dioxide

platinum

platinum(II) sulfide

tellurium

Refernces

• 1、 Turrentine, J. W.. "". . p. 385 - 385. Retrieved 1912.
• 2、 Chusova, Tamara P.,Semenova, Zinaida I.. "Thermodynamics of the Pt-Cl system". . p. 59 - 64. Retrieved 2008/10/09.
• 3、 Von Schnering, Hans Georg,Chang, Jen-Hui,Peters, Karl,Peters, Eva-Maria,Wagner, Frank R.,Grin, Yuri,Thiele, Gerhard. "Structure and bonding of the hexameric platinum(II) dichloride, Pt6Cl12 (β-PtCl2)". . p. 516 - 522. Retrieved 2008/10/08.