Tetrabutylammoniumcyanoborohydride

Base Information

• Chemical Name: Tetrabutylammoniumcyanoborohydride
• CAS No.: 43064-96-6
• Molecular Formula: C16H36N.CH3BN
• Molecular Weight: 282.321
• Hs Code.: 29310099
• European Community (EC) Number: 256-073-6
• DSSTox Substance ID: DTXSID50195672
• Mol file: 43064-96-6.mol

Synonyms:43064-96-6;Tetrabutylammonium cyanoborohydride;tetrabutylammoniumcyanoborohydride;CID 11780989;SCHEMBL57862;DTXSID50195672;AKOS015966252;FT-0639828

Chemical Property of Tetrabutylammoniumcyanoborohydride

Chemical Property:

• Appearance/Colour: White solid.
• Melting Point: 143-147 ºC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: g/cm³
• LogP: 3.83648
• Storage Temp.: water-free area
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 279.2971543
• Heavy Atom Count: 20
• Complexity: 147

Purity/Quality:

99% ^*data from raw suppliers

Tetrabutylammonium cyanoborohydride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,F
• Statements: 36/37/38-15
• Safety Statements: 26-36-7/8-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [B-]C#N.CCCC[N+](CCCC)(CCCC)CCCC
• Uses: Tetrabutylammonium Cyanoborohydride is used in preparation method of novel biomass plastic material. Reactant for:Hydroxymethylation reactionsRadical carbonylation reactionsReduction reactions (reductant)

Technology Process of Tetrabutylammoniumcyanoborohydride

There total 1 articles about Tetrabutylammoniumcyanoborohydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetra(n-butyl)ammonium hydrogensulfate (32503-27-8) + sodium cyanoborohydride (25895-60-7) → tetrabutylammonium (cyano)trihydroborate (43064-96-6)

Guidance literature:

In water;

DOI:10.1021/ja00799a058

Reference yield: 55.0%

2,6-dimethyl morpholine (141-91-3) + 3-(4-chlorophenyl)cyclopentanecarboxaldehyde (115169-80-7) + tetrabutylammonium (cyano)trihydroborate (43064-96-6) → 4-[3-(4-chlorophenyl)cyclopentylmethyl]-2,6-cis-dimethylmorpholine

Guidance literature:

With hydrogenchloride; silica gel; In methanol; dichloromethane;

Reference yield: 23.0%

3-(4-trimethylsilylphenyl)cyclobutanecarboxaldehyde (115169-60-3) + tetrabutylammonium (cyano)trihydroborate (43064-96-6) + cis-2,6-dimethylmorpholine (141-91-3,6485-45-6,6485-55-8) → 4-[ trans-3-(4-trimethylsilylphenyl)cyclobutylmethyl]-cis-2,6-dimethylmorpholine (115225-09-7)

Guidance literature:

With hydrogenchloride; silica gel; In methanol; dichloromethane;

upstream raw materials:

tetra(n-butyl)ammonium hydrogensulfate

sodium cyanoborohydride

Downstream raw materials:

2-[3-phenyl-3-(pyrrolidin-1-yl)-propyl]-3-carboethoxy-5-carbomethoxy-4-(m-nitrophenyl)-6-methyl-1,4-dihydropyridine

4-[ trans-3-(4-trimethylsilylphenyl)cyclobutylmethyl]-cis-2,6-dimethylmorpholine

1-adamantanemethanol

1-adamantaneglycolonitrile