N-(1-Naphthyl)-N,N'-diphenylbenzidine

Base Information

• Chemical Name: N-(1-Naphthyl)-N,N'-diphenylbenzidine
• CAS No.: 352359-41-2
• Molecular Formula: C₃₄H₂₆N₂
• Molecular Weight: 462.594
• Mol file: 352359-41-2.mol

Synonyms:N-(1-Naphthyl)-N,N'-diphenylbenzidine

Chemical Property of N-(1-Naphthyl)-N,N'-diphenylbenzidine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(1-Naphthyl)-N,N'-diphenylbenzidine

There total 7 articles about N-(1-Naphthyl)-N,N'-diphenylbenzidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

N-(4’-bromo-[1,1‘-biphenyl]-4-yl)-N-phenylnaphthalen-1-amine (352359-42-3) + aniline (62-53-3) → N-(1-Naphthyl)-N,N'-diphenylbenzidine (352359-41-2)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 100 ℃; for 6h;

DOI:10.1021/ma048365h

Reference yield: 82.0%

4-chlorobiphenyl-N-phenyl-N-1-naphthylamine (880800-31-7) + aniline (62-53-3) → N-(1-Naphthyl)-N,N'-diphenylbenzidine (352359-41-2)

Guidance literature:

With tri-tert-butyl phosphine; sodium t-butanolate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; for 7h; Inert atmosphere; Reflux;

Reference yield: 40.0%

1-Bromonaphthalene (90-11-9) + N,N'-diphenyl-p-phenylenediamine (531-91-9) → N-(1-Naphthyl)-N,N'-diphenylbenzidine (352359-41-2)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate; palladium diacetate; In toluene; for 46h; Heating;

DOI:10.1135/cccc20001403

upstream raw materials:

N-(4’-bromo-[1,1‘-biphenyl]-4-yl)-N-phenylnaphthalen-1-amine

aniline

tri-tert-butyl phosphine

sodium t-butanolate

Downstream raw materials:

N-(1-naphthyl)-N,N'-diphenyl-N'-(4-((4-vinylphenyl)methoxymethyl)phenyl)benzidine

N-(1-naphthyl)-N,N'-diphenyl-N'-(4-(hydroxymethyl)phenyl)benzidine

Refernces

• 1、 Sivasubramaniam, Varatharajan,Brodkorb, Florian,Hanning, Stephanie,Loebl, Hans Peter,van Elsbergen, Volker,Boerner, Herbert,Scherf, Ullrich,Kreyenschmidt, Martin. "Fluorine cleavage of the light blue heteroleptic triplet emitter FIrpic". . p. 640 - 649. Retrieved 2009.
• 2、 -. "AROMATIC AMINE DERIVATIVES AND ELECTROLUMINESCENCE DEVICE USING THE SAME". . . Retrieved 2008/06/13.