Zinc nitrate hexahydrate

Base Information

• Chemical Name: Zinc nitrate hexahydrate
• CAS No.: 10196-18-6
• Molecular Formula: Zn(NO3)2^.6(H2O)
• Molecular Weight: 189.4
• Hs Code.: 28342990
• European Community (EC) Number: 600-255-3
• Mol file: 10196-18-6.mol

Synonyms:zinc nitrate;zinc nitrate hexahydrate;zinc nitrate, (65)Zn-labeled

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Chemical Property of Zinc nitrate hexahydrate

Chemical Property:

• Appearance/Colour: white crystal
• Melting Point: 36 °C(lit.)
• Boiling Point: 105～131oC (-6H2O)
• PSA: 193.14000
• Density: 2.065 g/mL at 25 °C(lit.)
• LogP: 0.17990
• Sensitive.: Hygroscopic
• Solubility.: water: soluble(lit.)
• Water Solubility.: 1800 G/L (20 ºC)
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 295.968166
• Heavy Atom Count: 15
• Complexity: 18.8

Purity/Quality:

Safty Information:

• Pictogram(s): O, Xn
• Hazard Codes: O,Xn
• Statements: 8-22-36/37/38-38
• Safety Statements: 17-26-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Zn+2]
• Physical Properties: The hexahydrate, Zn(NO3)2?6H2O, is a colorless and odorless crystalline solid; tetragonal structure; density 2.065 g/cm3 at 15°C; melts at 36.4°C; loses all its water of crystallization between 105 to 131°C; very soluble in water, about 184 g/100mL water at 20°C; the aqueous solution acidic, the pH of a 5% solution is about 5.1; also very soluble in alcohol. The trihydrate, Zn(NO3)2?3H2O consists of colorless needles; melts at 45.5°C; very soluble in water, 327 g/100mL at 40°C.
• Uses: The compound is used as a mordant in dyeing and as a latex coagulant. It also is used as an acid catalyst and as an analytical standard for zinc. Zinc Nitrate Hexahydrate is a component used in the composition for nourishing and protecting fruit trees from acid rain. Used as a mordant in dyeing and chemical synthesis of coordination polymers Zinc nitrate hexahydrate is used in the synthesis of coordination polymers. It is utilized in the preparation of zinc oxide based nanowires. It is also used as a mordant in dyeing. It is involved in the preparation of a new microporous, organically templated zinc phosphate, which finds application as catalysts and other applications involving microporosity.

Technology Process of Zinc nitrate hexahydrate

There total 38 articles about Zinc nitrate hexahydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.8%

C56H88N12O16Zn2 → zinc(II) nitrate (10196-18-6)

Guidance literature:

at 20 - 800 ℃;

DOI:10.1016/j.poly.2017.01.063

Reference yield: 55.2%

aluminum(III) nitrate nonahydrate + zinc (7440-66-6) → zinc(II) nitrate (10196-18-6) + [Al13(μ3-OH)6(μ-OH)18(H2O)24](NO3)15

Guidance literature:

In water; aq. soln. of Al(NO3)3*9H2O treated with Zn, stirred overnight; filtered, evapd., washed with isopropanol; monitored by XRD;

DOI:10.1021/ic200483q

Reference yield:

tetramethylammonium tetranitratozincate → zinc(II) nitrate (10196-18-6) + carbon dioxide (124-38-9,18923-20-1) + nitrogen(II) oxide (10102-43-9) + N,N-dimethyl-formamide (68-12-2,33513-42-7) + zinc(II) oxide

Guidance literature:

byproducts: CH2O, CH3OH, (CH3)3N; thermal decompn. (200-400° 5E-2 mmHg, heating rate 6 k min**-1); DTA, DTGA, TGA, mass spectrometry;

upstream raw materials:

nitric acid

zinc(II) carbonate

oxygen

dinitrogen pentoxide

Downstream raw materials:

zinc

zinc(II) thiocyanate

water

nitric acid

Refernces

• 1、 McGillicuddy, Ryan D.,Thapa, Surendra,Wenny, Malia B.,Gonzalez, Miguel I.,Mason, Jarad A.. "Metal-organic phase-change materials for thermal energy storage". . p. 19170 - 19180. Retrieved 2020.
• 2、 Masloboeva, S. M.,Palatnikov, M. N.,Smirnov, M. V.. "Sol-gel synthesis of lithium niobate doped by zinc and boron and study of the luminescent properties of ceramics LiNbO3: Zn: B". . p. 947 - 951. Retrieved 2020.
• 3、 Hazra, Subhenjit,Ghosh, Barun Kumar,Joshi, Hrishikesh Ravindra,Patra, Manoj Kumar,Jani, Raj Kumar,Vadera, Sampat Raj,Ghosh, Narendra Nath. "Development of a novel one-pot synthetic method for the preparation of (Mn0.2Ni0.4Zn0.4Fe2O4)x-(BaFe12O19)1-x nanocomposites and the study of their microwave absorption and magnetic properties". . p. 45715 - 45725. Retrieved 2014.
• 4、 Lumb, Isha,Sran, Balkaran Singh,Sood, Henna,Arora, Daljit Singh,Hundal, Geeta. "Coordination chemistry of Cu(II), Co(II), Zn(II) and Ag(I) complexes of isomeric pyridine 2- and 4-carboxamides and their biological activity evaluation". . p. 153 - 166. Retrieved 2017.
• 5、 Divers, Edward. "LXI. - On the production of hydroxylamine from nitric acid". . p. 443 - 466. Retrieved 1883.
• 6、 Gajbhiye, N. S.,Bhattacharya, U.,Darshane, V. S.. "Thermal decomposition of zinc-iron citrate precursor". . p. 219 - 230. Retrieved 1995.
• 7、 Cai,Jiang,Zhu,Wang. "High quality Al-doped ZnO thin films deposited using targets prepared by chemical coprecipitation". . p. 1461 - 1464. Retrieved 2009.