phenyliminobenzophenone

Base Information

• Chemical Name: phenyliminobenzophenone
• CAS No.: 574-45-8
• Molecular Formula: C19H15N
• Molecular Weight: 257.335
• Mol file: 574-45-8.mol

Synonyms:N-(Diphenylmethylene)aniline;N-(diphenylmethylidene)aniline;N-(diphenylmethylidene)phenylamine;Benzenamine, N-(diphenylmethylene)-;Benzophenone anil;Aniline,N-(diphenylmethylene);N-Benzhydrylideneaniline;Benzenamine,N-(diphenylmethylene);N-phenyl-(diphenylmethylidene)amine;Benzhydrylidene-phenyl-amine;N-(diphenylmethylene)benzenamine;

Chemical Property of phenyliminobenzophenone

Chemical Property:

• Vapor Pressure: 2.24E-05mmHg at 25°C
• Melting Point: 113-114 °C
• Boiling Point: 371.2°Cat760mmHg
• PKA: 2.75±0.50(Predicted)
• Flash Point: 170.6°C
• PSA: 12.36000
• Density: 0.99g/cm³
• LogP: 4.85570

Purity/Quality:

99% ^*data from raw suppliers

N-(Diphenylmethylene)aniline 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenyliminobenzophenone

There total 105 articles about phenyliminobenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

bromobenzene (108-86-1,52753-63-6) + Benzhydrylamine (91-00-9) → N-(diphenylmethylidene)phenylamine (574-45-8)

Guidance literature:

With caesium carbonate; iron(III) acetylacetonate; copper(II) oxide; In N,N-dimethyl-formamide; at 90 ℃; for 30h; Conversion of starting material; sealed tube;

Reference yield: 70.0%

benzophenone (119-61-9) + aniline (62-53-3) → N-(diphenylmethylidene)phenylamine (574-45-8) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

benzophenone; With potassium; In tetrahydrofuran;

aniline; In tetrahydrofuran; for 24h;

DOI:10.1007/s11178-005-0100-7

Reference yield: 63.0%

phenylmagnesium bromide + phenylcarbonimidic dichloride (622-44-6) → biphenyl (92-52-4,1594-86-1) + N-(diphenylmethylidene)phenylamine (574-45-8)

Guidance literature:

palladium; In tetrahydrofuran;

DOI:10.1016/S0040-4039(00)82873-7

upstream raw materials:

diethyl ether

acetic acid-(benzylidene-phenyl-hydrazide)

ethylmagnesium bromide

benzophenone N-phenylhydrazone

Downstream raw materials:

N-(diphenyl-pyridin-2-yl-methyl)-aniline

3-phenylcarbamoylacrylic acid

3-methyl-1,4,4-triphenyl-azetidin-2-one

tetrabenzo[5.5]fulvalene

Refernces

• 1、 Naegeli. "-". . p. 786. Retrieved 1899.
• 2、 Higuchi, Masayoshi,Kimoto, Atsushi,Shiki, Satoshi,Yamamoto, Kimihisa. "Selective Synthesis of Novel Cyclic Phenylazomethine Trimers". . p. 5680 - 5684. Retrieved 2000.
• 3、 Cardinale, Luana,Schmotz, Mattis-Ole W. S.,Konev, Mikhail O.,Jacobi von Wangelin, Axel. "Photoredox-Catalyzed Synthesis of α-Amino Acid Amides by Imine Carbamoylation". supporting information. p. 506 - 510. Retrieved 2022/01/20.
• 4、 Ye, Jian-Heng,Bellotti, Peter,Paulisch, Tiffany O.,Daniliuc, Constantin G.,Glorius, Frank. "Visible-Light-Induced Cycloaddition of α-Ketoacylsilanes with Imines: Facile Access to β-Lactams". supporting information. p. 13671 - 13676. Retrieved 2021/05/11.