oxoniobium trihydrochloride

Base Information

• Chemical Name: oxoniobium trihydrochloride
• CAS No.: 13597-20-1
• Molecular Formula: Cl3H3NbO
• Molecular Weight: 215.265
• Mol file: 13597-20-1.mol

Synonyms:

Chemical Property of oxoniobium trihydrochloride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of oxoniobium trihydrochloride

There total 88 articles about oxoniobium trihydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

oxygen (80937-33-3) + niobium pentachloride (10026-12-7) → niobium(V) oxide chloride (13597-20-1)

Guidance literature:

In neat (no solvent); sublimation of 2 g NbCl5 on glass wool in reaction tube, treatment with stream of dry O2 (20 cm**3/min) for 2h in tube with 20 mm diameter at 150°C;; sublimation in stream of O2 at 200°C to a tube zone which is maintained at 100°C;;

DOI:10.1016/0022-5088(59)90029-3

Reference yield:

columbite → niobium pentachloride (10026-12-7) + niobium(V) oxychloride (13597-20-1)

Guidance literature:

With chlorine; 320-500°C,1-2 h;

Reference yield:

disulfur dichloride (10025-67-9) + niobium(V) oxide → niobium(V) oxide chloride (13597-20-1) + niobium pentachloride (10026-12-7)

Guidance literature:

In further solvent(s); further solvent: S2Cl2; 300°C;; product mixture obtained;;

upstream raw materials:

sulfur dioxide

niobium pentachloride

niobium pentachloride

water

Downstream raw materials:

niobium pentachloride

carbon dioxide

niobium pentafluoride

hydrogenchloride

Refernces

• 1、 Beck, Johannes,Bordinhao, Jairo. "Polar [NbOCl3]2n and [NbOX4 -]n (X = Cl, Br) chains in the structures of NbOCl 3 and the thallium-halogenooxoniobates Tl[NbOCl4] and Tl[NbOBr4] - Synthesis, crystal structures and optical second harmonic generation". . p. 1261 - 1266. Retrieved 2005.
• 2、 Ebitani, Kokhi,Hirano, Yoshiaki,Morikawa, Akira. "". . p. 379 - 385. Retrieved 1995.
• 3、 Bortoluzzi, Marco,Ghini, Franco,Hayatifar, Mohammad,Marchetti, Fabio,Pampaloni, Guido,Zacchini, Stefano. "Oxido- and sulfidoniobium(V) N,N-diethylcarbamates: Synthesis, characterization and DFT study". . p. 3112 - 3118. Retrieved 2013.
• 4、 Gibson, Vernon C.,Kee, Terence P.,Shaw, Alan. "". . p. 2217 - 2220. Retrieved 1988.
• 5、 Stroebele, Markus,Meyer, Hans-Juergen. "Revised crystal structure of NbOCl3". . p. 488 - 491. Retrieved 2002.
• 6、 Chiera, Nadine M.,Sato, Tetsuya K.,Tomitsuka, Tomohiro,Asai, Masato,Suzuki, Hayato,Tokoi, Katsuyuki,Toyoshima, Atsushi,Tsukada, Kazuaki,Nagame, Yuichiro. "Formation and thermochemical properties of oxychlorides of niobium (Nb) and tantalum (Ta): Towards the gas-phase investigation of dubnium (Db) oxychloride". . p. 361 - 366. Retrieved 2019.