Thioquinox

Base Information

• Chemical Name: Thioquinox
• CAS No.: 93-75-4
• Molecular Formula: C9H4 N2 S3
• Molecular Weight: 236.342
• Hs Code.: 29349990
• European Community (EC) Number: 202-272-8
• UNII: 0DRA4L621C
• DSSTox Substance ID: DTXSID3042471
• Nikkaji Number: J4.684A
• Wikidata: Q15628428
• Metabolomics Workbench ID: 56018
• Mol file: 93-75-4.mol

Synonyms:THIOQUINOX;Quinothionate;93-75-4;Chinothionat;Thiaquinox;Readex;Eradex;[1,3]dithiolo[4,5-b]quinoxaline-2-thione;Thioquinox [ISO];Bayer 30686;1,3-Dithiolo[4,5-b]quinoxaline-2-thione;Caswell No. 720;Quinoxaline-2,3-diyl trithiocarbonate;2-Thioxo-1,3-dithiolo(4,5-b)quinoxaline;2,3-Quinoxalinedithiol cyclic-trithiocarbonate;BAY 30686;2,3-Quinoxalinedithiol, cyclic trithiocarbonate;ENT 25,579;SS 1451;2-Thio-1,3-dithio(4,5-b)quinoxaline;Trithiocarbonic acid, cyclic ester with 2,3-quinoxalinedithiol;HSDB 1761;Carbonic acid, trithio-, cyclic 2,3-quinoxalinediyl ester;Chinoxalin-2,3-diyl-trithiocarbonat;EINECS 202-272-8;EPA Pesticide Chemical Code 084401;BRN 0521713;UNII-0DRA4L621C;1,3-Dithiolo(4,5-b)quinoxaline-2-thione;AI3-25579;Chinoxalin-2,3-dithiol-cyclo-thio-carbonat;0DRA4L621C;Chinoxalin-2,3-diyl-trithiocarbonat [German];Carbonic acid, trithio-, cyclic ester with 2,3-quinoxalinedithiol;Chinoxalin-2,3-dithiol-cyclo-thio-carbonat [German];2-Thio-1,3-dithio[4,5-b]quinoxaline;Eraditon;Erazidon;THIOQUINOX [MI];SCHEMBL54635;C9H4N2S3;DTXSID3042471;CHEBI:38822;C9-H4-N2-S3;LS-52137;C18946;Q15628428;1,3-DITHIOLO(4,5-B)QUINOXALINE-2-THIONE [HSDB];CARBONIC ACID, TRITHIO-, CYCLIC ESTER WITH 2,3- QUINOXALINEDITHIOL;TRITHIOCARBONIC ACID, CYCLIC ESTER WITH 2,3- QUINOXALINEDITHIOL

Chemical Property of Thioquinox

Chemical Property:

• Vapor Pressure: 1.69E-08mmHg at 25°C
• Melting Point: 180°
• Boiling Point: 468.4°C at 760 mmHg
• Flash Point: 237.1°C
• PSA: 114.35000
• Density: 1.68g/cm³
• LogP: 3.63550
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 235.95366166
• Heavy Atom Count: 14
• Complexity: 234

Purity/Quality:

Thioquinox ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 24

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Pesticides -> Other Insecticides
• Canonical SMILES: C1=CC=C2C(=C1)N=C3C(=N2)SC(=S)S3
• Uses: Acaricide, fungicide. Thioquinox is a fungicide/insecticide used in pesticide formulations. Toxic to various species of mites. A member of the quinoxoline class of pesticides.

Technology Process of Thioquinox

There total 3 articles about Thioquinox which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-dichloroquinoxaline (2213-63-0) → 2-thio-1,3-dithiolo[4,5-b]quinoxaline (93-75-4)

Guidance literature:

Multi-step reaction with 2 steps

1: KHS / H₂O / Heating

2: benzene

With potassium hydrosulfide; In water; benzene;

Reference yield:

thiophosgene (463-71-8) + quinoxaline-2,3-dithiole (1199-03-7) → 2-thio-1,3-dithiolo[4,5-b]quinoxaline (93-75-4)

Guidance literature:

In benzene;

Reference yield:

→ 2-thio-1,3-dithiolo[4,5-b]quinoxaline (93-75-4)

Guidance literature:

2.3-Dimercapto-chinoxalin, Thiophosgen;

upstream raw materials:

thiophosgene

quinoxaline-2,3-dithiole

2,3-dichloroquinoxaline

Refernces

• 1、 -. "Animal coccidiosis preventive". . . Retrieved 2008/06/13.