Triallyl phosphite

Base Information

• Chemical Name: Triallyl phosphite
• CAS No.: 102-84-1
• Molecular Formula: C9H15 O3 P
• Molecular Weight: 202.19
• Hs Code.: 2920901900
• European Community (EC) Number: 203-060-8
• NSC Number: 44606
• UNII: ZJ3PN55SHG
• DSSTox Substance ID: DTXSID3059262
• Nikkaji Number: J56.162B
• Wikidata: Q72509575
• Mol file: 102-84-1.mol

Synonyms:Triallyl phosphite;102-84-1;Triallylphosphite;Allyl phosphite;Triallyloxyphosphine;tris(prop-2-enyl) phosphite;Phosphorous acid, tri-2-propenyl ester;Phosphorous acid, tri-2-propen-1-yl ester;Phosphorous acid, triallyl ester;Allyl phosphite, (C3H5O)3P;EINECS 203-060-8;NSC 44606;ZJ3PN55SHG;AI3-51075;NSC-44606;C9H15O3P;triallylphosphit-;tris(prop-2-en-1-yl) phosphite;UNII-ZJ3PN55SHG;SCHEMBL88171;Allyl phosphite (6CI,7CI);Phosphorous acid triallyl ester;DTXSID3059262;C9-H15-O3-P;NSC44606;MFCD00014948;AKOS024362734;LS-109026;FT-0707249

Chemical Property of Triallyl phosphite

Chemical Property:

• Vapor Pressure: 0.437mmHg at 25°C
• Boiling Point: 201.4 ºC at 760 mmHg
• Flash Point: 86.7 ºC
• PSA: 41.28000
• Density: g/cm³
• LogP: 2.82110
• Sensitive.: Air & Moisture Sensitive
• Solubility.: Not miscible or difficult to mix.
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 202.07588133
• Heavy Atom Count: 13
• Complexity: 130

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triallyl phosphite 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison by ingestion and skin contact. A mild eye irritant.
• Hazard Codes: A poison by ingestion and skin contact. A mild eye irritant.
• Statements: 20/21/22-36/37/38
• Safety Statements: 23-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOP(OCC=C)OCC=C
• Uses: Triallyl phosphite is employed as a radical precursor.

Technology Process of Triallyl phosphite

There total 4 articles about Triallyl phosphite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

diallylcarbonate (15022-08-9) → triallyl phosphite (102-84-1)

Guidance literature:

With phosphorus trichloride; In 1,4-dioxane; at 90 ℃; for 5h; Large scale;

Reference yield:

allyl alcohol (107-18-6) → triallyl phosphite (102-84-1)

Guidance literature:

With diethyl ether; phosphorus trichloride; beim Behandeln mit einem tertiaeren Amin;

DOI:10.1039/jr9590002272 DOI:10.1002/app.1959.070010321 DOI:10.1021/ja01591a026

Reference yield:

triphenyl phosphite (101-02-0) + allyl alcohol (107-18-6) → triallyl phosphite (102-84-1)

Guidance literature:

With sodium hydroxide;

upstream raw materials:

triphenyl phosphite

allyl alcohol

diallylcarbonate

Downstream raw materials:

triallyl phosphate

diallyl benzylphosphonate

diallyl phosphite

3-chloroprop-1-ene

Refernces

• 1、 Moore, Joel D.,Sprott, Kevin T.,Wrobleski, Aaron D.,Hanson, Paul R.. "Double diastereoselective intramolecular cyclopropanation to P-chiral [3.1.0]-bicyclic phosphonates". . p. 2357 - 2360. Retrieved 2002.
• 2、 -. "Xanthene dye compounds and photoresist composition containing the same". Paragraph 0107; 0115; 0116. . Retrieved 2018/02/10.