3-chlorophenyl fluorosulfonate

Base Information

• Chemical Name: 3-chlorophenyl fluorosulfonate
• CAS No.: 1535-32-6
• Molecular Formula: C₆H₄ClFO₃S
• Molecular Weight: 210.613
• Mol file: 1535-32-6.mol

Synonyms:3-chlorophenyl fluorosulfonate

Chemical Property of 3-chlorophenyl fluorosulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-chlorophenyl fluorosulfonate

There total 2 articles about 3-chlorophenyl fluorosulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

3-monochlorophenol (108-43-0) → 3-chlorophenyl fluorosulfonate (1535-32-6)

Guidance literature:

With potassium fluoride; triethylamine; N,N`-sulfuryldiimidazole; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 18h;

DOI:10.1002/anie.201911465

Reference yield:

→ 3-chlorophenyl fluorosulfonate (1535-32-6)

Guidance literature:

Aus Thermolyse von m-Chlorophenoxythionyltrifluorid;

Reference yield: 95.0%

3-chlorophenyl fluorosulfonate (1535-32-6) + aniline (62-53-3) → 3-chlorodiphenylamine (101-17-7)

Guidance literature:

With η⁵‐cyclopentadienyl‐η³‐1‐phenylallylpalladium; potassium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In 1,4-dioxane; at 80 ℃; for 12h; Reagent/catalyst; Temperature; Solvent;

DOI:10.1021/acscatal.6b00865

upstream raw materials:

3-monochlorophenol

Downstream raw materials:

m-chlorobiphenyl

3-chlorodiphenylamine

3-chlorofluorobenzene

1-(sec-butyl)-3-chlorobenzene

Refernces

• 1、 Mendel, Marvin,Kalvet, Indrek,Hupperich, Daniel,Magnin, Guillaume,Schoenebeck, Franziska. "Site-Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO2F) Enabled by an Air-Stable PdI Dimer". supporting information. p. 2115 - 2119. Retrieved 2020/01/02.
• 2、 Hanley, Patrick S.,Krasovskiy, Arkady L.,Ober, Matthias S.,Whiteker, Gregory T.,Kruper, William J.. "Nickel- and Palladium-Catalyzed Coupling of Aryl Fluorosulfonates with Aryl Boronic Acids Enabled by Sulfuryl Fluoride". . p. 5041 - 5046. Retrieved 2015/09/15.