tris(triphenylphosphine)chloroiridium

Base Information

• Chemical Name: tris(triphenylphosphine)chloroiridium
• CAS No.: 16070-58-9
• Molecular Formula: C₅₄H₄₅ClIrP₃
• Molecular Weight: 1014.55
• Mol file: 16070-58-9.mol

Synonyms:tris(triphenylphosphine)chloroiridium

Chemical Property of tris(triphenylphosphine)chloroiridium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(triphenylphosphine)chloroiridium

There total 1 articles about tris(triphenylphosphine)chloroiridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

iridium (III) chloride (10025-83-9) + triphenylphosphine (603-35-0) → tris(triphenylphosphine)chloroiridium (16070-58-9)

Guidance literature:

In tert-butyl alcohol; PPh3 dissolved in hot t-butyl alc., purged with N2, IrCl3 added, refluxed for 72 h under N2; filtered, washed (ether), dried (air);

DOI:10.1021/ic034785w

Reference yield: 99.4%

nido-decaborane (17702-41-9) + tris(triphenylphosphine)chloroiridium (16070-58-9) → nido-6-iridadecaborane (82106-45-4)

Guidance literature:

nido-decaborane; With potassium hydroxide; In methanol; Inert atmosphere;

tris(triphenylphosphine)chloroiridium; In diethyl ether; Inert atmosphere;

DOI:10.1039/d1dt02971a

Reference yield: 90.0%

tris(triphenylphosphine)chloroiridium (16070-58-9) + {NEt4}{10-endo-{Au(PPh3)}-7,8-nido-C2B9H9Me2} → {IrAuH(μ-σ,η3-C2B9H8Me2)(PPh3)3}

Guidance literature:

With TlBF₄; In tetrahydrofuran;

DOI:10.1039/c39910001664

upstream raw materials:

iridium (III) chloride

triphenylphosphine

Downstream raw materials:

1,1-(PPh₃)2-1-H-1,2,4-IrC₂B₈H₁₀

closo-{2,2-(PPh₃)2-2-H-1,2-IrSeB₁₀H₁₀}

5,9,9-tris(triphenylphosphine)-6,9-carbiridadecaborane⁽¹⁴⁾

{sym-6,6,6-H(PPh₃)(Ph₂-ortho-C₆H₄)-nido-6-IrB₉H₁₂-5}

Refernces