1-m-tolylpentane

Base Information

• Chemical Name: 1-m-tolylpentane
• CAS No.: 1595-08-0
• Molecular Formula: C₁₂H₁₈
• Molecular Weight: 162.275
• Mol file: 1595-08-0.mol

Synonyms:1-m-tolylpentane

Chemical Property of 1-m-tolylpentane

Chemical Property:

Purity/Quality:

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Technology Process of 1-m-tolylpentane

There total 9 articles about 1-m-tolylpentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-penten (109-67-1) + toluene (108-88-3,15644-74-3,16713-13-6) → decane (124-18-5) + 1-methyl-4-n-pentylbenzene (1595-09-1) + 1-methyl-4-(2-pentyl)benzene (13633-04-0) + 1-m-tolylpentane (1595-08-0) + 2-m-tolylpentane

Guidance literature:

With C₈H₁₄O₄Rh₂; copper(II) dipivaloate; at 150 ℃; Reagent/catalyst; Temperature; Glovebox; Inert atmosphere;

DOI:10.1021/acs.organomet.9b00535

Reference yield:

1-penten (109-67-1) + 1-Methyl-4-((E)-pent-1-enyl)-benzene (7642-17-3,81392-97-4,82237-94-3) + toluene (108-88-3,15644-74-3,16713-13-6) → decane (124-18-5) + 1-methyl-4-n-pentylbenzene (1595-09-1) + 1-methyl-4-(2-pentyl)benzene (13633-04-0) + 1-m-tolylpentane (1595-08-0) + 2-m-tolylpentane

Guidance literature:

With copper(II) dipivaloate; at 150 ℃; for 24h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.organomet.9b00535

Reference yield:

1-penten (109-67-1) + C12H16 + toluene (108-88-3,15644-74-3,16713-13-6) → decane (124-18-5) + 1-methyl-4-n-pentylbenzene (1595-09-1) + 1-methyl-4-(2-pentyl)benzene (13633-04-0) + 1-m-tolylpentane (1595-08-0) + 2-m-tolylpentane

Guidance literature:

With copper(II) dipivaloate; at 150 ℃; for 24h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.organomet.9b00535

upstream raw materials:

1-bromo-butane

1-bromomethyl-3-methyl-benzene

amyl iodide

m-tolylmagnesium bromide

Refernces

• 1、 Pekel, ?zgen ?mür,Erdik, Ender. "Reactivity of mixed organozinc and mixed organocopper reagents: 6. Nickel-catalyzed coupling of methylarylzincs with primary alkyl halides; An atom-economic aryl-alkyl coupling". experimental part. p. 7087 - 7090. Retrieved 2012/01/06.