4-CH₃OC₆H₄BCl₂

Base Information

• Chemical Name: 4-CH₃OC₆H₄BCl₂
• CAS No.: 7294-69-1
• Molecular Formula: C₇H₇BCl₂O
• Molecular Weight: 188.849
• Mol file: 7294-69-1.mol

Synonyms:4-CH₃OC₆H₄BCl₂

Chemical Property of 4-CH₃OC₆H₄BCl₂

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-CH₃OC₆H₄BCl₂

There total 5 articles about 4-CH₃OC₆H₄BCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2,4,6-tris(4-methoxyphenyl)boroxine (7294-51-1) + boron trichloride (10294-34-5) → 4-CH3OC6H4BCl2 (7294-69-1)

Guidance literature:

In dichloromethane; chloroform; (-B(C6H4-4-OCH3)-O)3 in sol.of methylene dichlorid-chloroform (1:1) at -80°C and BCl3 at -39°C keeping at -80°C 18h; vac.distn;

Reference yield:

tris(p-anisyl)antimony (21502-70-5) + boron trichloride (10294-34-5) → 4-CH3OC6H4BCl2 (7294-69-1)

Guidance literature:

In dichloromethane; at 0 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2015.04.017

Reference yield:

2,4,6-tris(4-methoxyphenyl)boroxine (7294-51-1) → 4-CH3OC6H4BCl2 (7294-69-1)

Guidance literature:

With boron trichloride;

upstream raw materials:

2,4,6-tris(4-methoxyphenyl)boroxine

bis(p-anisyl)mercury

boron trichloride

tris(p-anisyl)antimony

Downstream raw materials:

4-CH₃OC₆H₄B(O-n-C₄H₉)2

(n-C₄H₉O)BClC₆H₄-4-OCH₃

(4-CH₃OC₆H₄)BClN(C₂H₅)2

4-CH₃OC₆H₄BClN(CH₃)(CH₂C₆H₅)

Refernces