Diethylene glycol divinyl ether

Base Information

• Chemical Name: Diethylene glycol divinyl ether
• CAS No.: 764-99-8
• Deprecated CAS: 1532529-11-5
• Molecular Formula: C8H14O3
• Molecular Weight: 158.197
• Hs Code.: 2909 19 90
• European Community (EC) Number: 212-133-3
• NSC Number: 6117
• UNII: ABM90Y2G95
• DSSTox Substance ID: DTXSID6044985
• Nikkaji Number: J34.760D
• Wikidata: Q27273849
• ChEMBL ID: CHEMBL3183169
• Mol file: 764-99-8.mol

Synonyms:Diethylene glycol divinyl ether;764-99-8;Divinylcarbitol;Dvedeg;Diethyleneglycoldivinylether;Dvedeg [Russian];3,6,9-Trioxaundeca-1,10-diene;Ethene, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-;Ether, bis[2-(vinyloxy)ethyl];NSC 6117;Divinyl ether diethylenglykolu;1-ethenoxy-2-(2-ethenoxyethoxy)ethane;Bis(2-(vinyloxy)ethyl) ether;Bis[2-(vinyloxy)ethyl] ether;EINECS 212-133-3;Ethene, 1,1'-(oxybis(2,1-ethanediyloxy))bis-;Divinyl ether diethylenglykolu [Czech];BRN 1752316;UNII-ABM90Y2G95;ABM90Y2G95;DTXSID6044985;NSC-6117;ETHER, BIS(2-VINYLOXYETHYL);1,1'-(Oxybis(ethyleneoxy))diethylene;(2-(2-(vinyloxy)ethoxy)ethoxy)ethene;{2-[2-(Ethenyloxy)ethoxy]ethoxy}ethene;Diethylene glycol divinyl ether, stab. 0.1% potassium hydroxide;EC 212-133-3;1,1'-[oxybis(ethyleneoxy)]diethylene;ETHER, BIS(2-(VINYLOXY)ETHYL);(2-(2-(ETHENYLOXY)ETHOXY)ETHOXY)ETHENE;Di(ethylene glycol) divinyl ether;diethyleneglycol divinyl ether;Divinyl Carbitol;SCHEMBL37264;3,9-Trioxaundeca-1,10-diene;CHEMBL3183169;DTXCID4024985;WLN: 1U1O2O2O1U1;NSC6117;Tox21_301264;MFCD00054610;AKOS015904283;Di(ethylene glycol) divinyl ether, 99%;NCGC00256188-01;AS-15370;CAS-764-99-8;LS-67750;CS-0031637;D0498;Ethene,1'-[oxybis(2,1-ethanediyloxy)]bis-;FT-0624895;1-(2-[2-(Vinyloxy)ethoxy]ethoxy)ethylene #;D89666;Etileno, 1,1'-[oxibis (2,1-etanodiiloxi)] bis-;Q27273849

Chemical Property of Diethylene glycol divinyl ether

Chemical Property:

• Vapor Pressure: 0.000213mmHg at 25°C
• Melting Point: -21 °C
• Refractive Index: n20/D 1.446(lit.)
• Boiling Point: 195.4 °C at 760 mmHg
• Flash Point: 62.2 °C
• PSA: 27.69000
• Density: 0.931 g/cm³
• LogP: 1.32320
• Storage Temp.: Store below +30°C.
• Sensitive.: Light Sensitive
• Water Solubility.: Insoluble in water.
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 8
• Exact Mass: 158.094294304
• Heavy Atom Count: 11
• Complexity: 89.5

Purity/Quality:

99.9% ^*data from raw suppliers

Diethylene glycol divinyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: R36/38:Irritating to eyes and skin.
• Statements: 36/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=COCCOCCOC=C
• Uses: Diethylene glycol divinyl ether is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Technology Process of Diethylene glycol divinyl ether

There total 8 articles about Diethylene glycol divinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

→ diethylene glycol divinyl ether (764-99-8,50856-26-3)

Guidance literature:

Reference yield: 66.3%

ethyleneglycol vinyl ether (764-48-7) + 2-chloroetyl vinyl ether (110-75-8) → diethylene glycol divinyl ether (764-99-8,50856-26-3)

Guidance literature:

With sodium hydroxide; tributyl-amine; at 90 ℃; for 8h;

Reference yield: 32.0%

2-[2-(ethenyloxy)ethoxy]ethan-1-ol (929-37-3) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → diethylene glycol divinyl ether (764-99-8,50856-26-3)

Guidance literature:

With potassium hydroxide; at 20 ℃; for 5h;

DOI:10.1023/A:1019687828252

upstream raw materials:

acetylene

diethylene glycol

-butyl vinyl ether

ethyleneglycol vinyl ether

Downstream raw materials:

1-<2-(2-vinyloxyethoxy)ethoxy>ethyl acrylate

diphenethyl(12-phenethyl-14-phenyl-12-thioxo-3,6,9-trioxa-12λ⁵-phosphatetradecyl)phosphine Sulfide_No.No._

12,12-diphenyl-12-thioxo-3,6,9-trioxa-12λ5-phosphadodecyl(diphenyl)phosphine sulfide

2-(2-{2-[bis(4-chlorophenethyl)phosphino]ethoxy}ethoxy)ethyl 2-[bis(4-chlorophenethyl)phosphino]ethyl ether

Refernces

• 1、 -. "Purification of alkenyl compounds". Page column 8. . Retrieved 2008/06/13.
• 2、 Trofimov, B. A.,Skotheim, T. A.,Parshina, L. N.,Khil'ko, M. Ya.,Oparina, L. A.,Kovalev, L. P.,Gavrilov, A. B.. "Sulfurization of polymers 1. The reaction of polydialkylsiloxanes with elemental sulfur and electrochemical behavior of the products". . p. 463 - 469. Retrieved 2007/10/03.