diethyl ketone enol isobutyrate

Base Information

• Chemical Name: diethyl ketone enol isobutyrate
• CAS No.: 83710-44-5
• Molecular Formula: C₉H₁₆O₂
• Molecular Weight: 156.225
• Mol file: 83710-44-5.mol

Synonyms:diethyl ketone enol isobutyrate

Chemical Property of diethyl ketone enol isobutyrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl ketone enol isobutyrate

There total 2 articles about diethyl ketone enol isobutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-trimethylsilyloxy-2-pentene (17510-47-3) + isobutyryl chloride (79-30-1) → dodecane (112-40-3) + 2,4-dimethyl-heptane-3,5-dione (37484-68-7) + diethyl ketone enol isobutyrate (83710-44-5)

Guidance literature:

With zinc(II) chloride; In diethyl ether; dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/jo00147a011

Reference yield:

3-trimethylsilyloxy-2-pentene (17510-47-3) + isobutyryl chloride (79-30-1) → 2,4-dimethyl-heptane-3,5-dione (37484-68-7) + diethyl ketone enol isobutyrate (83710-44-5)

Guidance literature:

With bismuth(III) chloride; zinc(II) iodide; In diethyl ether; dichloromethane; for 0.5h; Ambient temperature; other reagent: bismuth(III) chloride;

DOI:10.1021/jo960090j

upstream raw materials:

3-trimethylsilyloxy-2-pentene

isobutyryl chloride

Refernces

• 1、 Tirpak, Robin E.,Rathke, Michael W.. "Acylation of Ketone Silyl Enol Ethers with Acid Chlorides. Synthesis of 1,3-Diketones". . p. 5099 - 5102. Retrieved 2007/10/02.