Cuprouschloride

Base Information

• Chemical Name: Cuprouschloride
• CAS No.: 7758-89-6
• Deprecated CAS: 11093-68-8,12258-96-7,12622-24-1,53906-70-0,53906-71-1,53906-72-2,53906-73-3
• Molecular Formula: ClCu
• Molecular Weight: 98.999
• Hs Code.: 2827.39
• UNII: C955P95064
• DSSTox Substance ID: DTXSID5035242
• Nikkaji Number: J43.794H
• Mol file: 7758-89-6.mol

Synonyms:Cuprouschloride;copper(1+);chloride;75763-85-8;Nantokite;Cu(II) chloride;CUPROUS CHLORIDE [MI];DTXSID5035242;AKOS015904522;C2162

Chemical Property of Cuprouschloride

Chemical Property:

• Appearance/Colour: white or pale grey powder
• Vapor Pressure: 1.3 mm Hg ( 546 °C)
• Melting Point: 430 °C(lit.)
• Refractive Index: 1.93
• Boiling Point: 1490 °C(lit.)
• Flash Point: 1490oC
• PSA: 0.00000
• Density: 1.15 g/mL at 20 °C
• LogP: -2.99850
• Storage Temp.: Store at +5°C to +30°C.
• Sensitive.: Air & Moisture Sensitive
• Solubility.: 0.06 g/L (25°C)
• Water Solubility.: 0.06 g/L (25 ºC)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 97.898450
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Copper(I) chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, N
• Hazard Codes: Xn,N
• Statements: 22-50/53-51/53-36/37/38-41-37/38-38
• Safety Statements: 26-61-60-22-39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cu+]
• Physical properties: White cubic crystal which turns blue when heated at 178°C; density 4.14 g/cm3; the mineral nantokite (CuCl) has density 4.14 g/cm3, hardness 2.5 (Mohs), refractive index 1.930; melts at 430°C becoming a deep, green liquid; vaporizes around 1,400°C; vapor pressure 5 torr at 645°C and 400 torr at 1,250°C; low solubility in water (decomposes partially); Ksp 1.72x10-7; insoluble in ethanol and acetone; soluble in concentrated HCl and ammonium hydroxide.
• Uses: Copper chloride is also known as cupric chloride, this substance was made by treating copper carbonate with hydrochloric acid. The greenish blue crystals are soluble in water, alcohol, and ether. This halide was added to printing-out and silver bromide emulsions for increased contrast. Copper(I) chloride (CuCl) or cuprous chloride is a white powder used as an absorbing agent for carbon dioxide gas in enclosed breathing areas such as space vehicles. As catalyst for organic reactions; catalyst, decolorizer and desulfuring agent in petroleum industry; in denitration of cellulose; as condensing agent for soaps, fats and oils; in gas analysis to absorb carbon monoxide. Shows unique character as an initiator of radical reactions such as the hydrostannation of α,β-unsaturated ketones.1 It is used for absorption of carbon monoxide in gas analysis.

Technology Process of Cuprouschloride

There total 8 articles about Cuprouschloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

→ copper(I) chloride (7758-89-6)

Guidance literature:

Reference yield:

→ copper(I) chloride (7758-89-6) + o-chlorobenzoyl chloride (609-65-4)

Guidance literature:

Reference yield:

copper dichloride → copper(I) chloride (7758-89-6) + Cl4Cu4 + (CuCl)3

Guidance literature:

In neat (no solvent); sublimation of CuCl2; not isolated, detected by MS;

DOI:10.1039/ft9908600603

upstream raw materials:

tetrachloromethane

copper

chlorine

Downstream raw materials:

(4R)-4-Methyloctanoic acid

(3S, 5R)-3-Amino-5-methyl-nonanoic acid

3,3-ethylenedioxy-5α,17α,20-trihydroxy-11β-[4-(N,N-dimethylamino)phenyl]-21-methoxy-19-norpregn-9-ene

([4-{2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-1,2,3,6-tetrahydropyrimidin-1-yl]phenoxy}phenoxy]methyl)benzene

Refernces

• 1、 -. "Preparation of biphenols by oxidative coupling of alkylphenols using a recyclable copper catalyst". . . Retrieved 2008/06/13.
• 2、 -. "Process for the preparation of dialkyl carbonates". . . Retrieved 2008/06/13.