Diphenyliodanium;hydrobromide

Base Information

• Chemical Name: Diphenyliodanium;hydrobromide
• CAS No.: 1483-73-4
• Molecular Formula: C12H10 I . Br
• Molecular Weight: 361.02
• Hs Code.: 29319090
• NSC Number: 8980
• Mol file: 1483-73-4.mol

Synonyms:diphenyliodanium;hydrobromide;SCHEMBL3169505;NSC8980;NSC-8980

Chemical Property of Diphenyliodanium;hydrobromide

Chemical Property:

• Appearance/Colour: LIGHT YELLOW POWDER
• Melting Point: 222.5-227.5 °C(lit.)
• Refractive Index: 1.6500 (estimate)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -3.18100
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Light Sensitive
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 360.90889
• Heavy Atom Count: 14
• Complexity: 116

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diphenyliodonium Bromide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 34-25-36/37/38
• Safety Statements: 26-36-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[I+]C2=CC=CC=C2.Br

Technology Process of Diphenyliodanium;hydrobromide

There total 9 articles about Diphenyliodanium;hydrobromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bis(phenyl)iodonium trifluoroacetate (16668-99-8) → diphenyliodonium bromide (1483-73-4)

Guidance literature:

With potassium bromide; In methanol; water; for 0.25h;

DOI:10.1002/adsc.202100426

Reference yield: 92.0%

diphenyliodonium iodide (2217-79-0) → diphenyliodonium bromide (1483-73-4)

Guidance literature:

With hydrogen bromide; dihydrogen peroxide; In methanol; water; Heating;

DOI:10.1246/bcsj.70.219

Reference yield: 77.0%

benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → diphenyliodonium bromide (1483-73-4)

Guidance literature:

benzene; With sodium periodate; sulfuric acid; iodine; In acetic anhydride; at 20 - 55 ℃; for 3h;

With potassium bromide; In water; for 1h;

DOI:10.1002/chem.201502995

upstream raw materials:

benzene

phenyllithium

(Dichloroiodo)benzene

triphenyl-iodan

Downstream raw materials:

N-phenylsaccharin

bromobenzene

iodobenzene

tert-butyl N-hydroxy-N-phenylcarbamate

Refernces

• 1、 Soldatova, Natalia,Postnikov, Pavel,Kukurina, Olga,Zhdankin, Viktor V.,Yoshimura, Akira,Wirth, Thomas,Yusubov, Mekhman S.. "One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid". supporting information. p. 849 - 855. Retrieved 2018/04/30.
• 2、 Li, Jian,Liu, Li,Ding, Dong,Sun, Jiang-Tao. "Halogen exchange via a halogenation of diaryliodonium salts with cuprous halide". . p. 541 - 548. Retrieved 2014/01/06.