Lithium dimethylamide

Base Information

• Chemical Name: Lithium dimethylamide
• CAS No.: 3585-33-9
• Molecular Formula: C2H7 N . Li
• Molecular Weight: 51.0173
• Hs Code.: 2924199090
• European Community (EC) Number: 222-714-3
• Nikkaji Number: J367.804K
• Mol file: 3585-33-9.mol

Synonyms:Lithium dimethylamide;3585-33-9;LiNMe2;MFCD00008295;lithium;dimethylazanide;Lithium dimethylamide, 95%;YDGSUPBDGKOGQT-UHFFFAOYSA-N;AKOS025295221;FT-0634914;Lithium dimethylamide preparation, 5 wt. % in hexanes

Chemical Property of Lithium dimethylamide

Chemical Property:

• Vapor Pressure: 1520mmHg at 25°C
• Boiling Point: 6.1°Cat760mmHg
• Flash Point: °C
• PSA: 3.24000
• Density: g/cm³
• LogP: 0.01230
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Reacts violently with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 51.06602763
• Heavy Atom Count: 4
• Complexity: 6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lithium dimethylamide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C,N,Xn
• Statements: 17-34-67-65-62-51/53-48/20-11-36/38
• Safety Statements: 9-16-26-29-33-36/37/39-45-62-27-61-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li+].C[N-]C
• Uses: It is used in the synthesis of some d0 organoimido complexes of the early transition metals and in meta rearrangement in the reaction of triphenyl-(p-bromophenyl)-silane.

Technology Process of Lithium dimethylamide

There total 9 articles about Lithium dimethylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Mo(NMe2)6Li2(THF)2 → lithium dimethylamide (3585-33-9) + tetrakis(dimethylamido)molybdenum(IV) (100207-68-9)

Guidance literature:

In benzene;

DOI:10.1016/S0277-5387(00)80489-1

Reference yield:

dimethyl amine (124-40-3) → lithium dimethylamide (3585-33-9)

Guidance literature:

With n-butyllithium;

Reference yield:

N,N-dimethylammonium chloride (506-59-2) → lithium dimethylamide (3585-33-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 14h; Inert atmosphere;

DOI:10.1021/acscatal.5b01671

upstream raw materials:

trityllithium

dimethyl amine

1-cyclopentenyllithium

3,4-dimethoxy-3-cyclobutene-1,2-dione

Downstream raw materials:

1-methoxy-3-methyl-benzene

ph3Si(ph-3-Nme₂)

(dimethylamino)triphenylsilane

trityllithium

Refernces

• 1、 Tuscher, Lars,Helling, Christoph,Ganesamoorthy, Chelladurai,Krüger, Julia,W?lper, Christoph,Frank, Walter,Nizovtsev, Anton S.,Schulz, Stephan. "Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane". . p. 12297 - 12304. Retrieved 2017.
• 2、 -. "Preparation method of beta-caraban". Paragraph 0057-0060; 0089-0090. . Retrieved 2021/11/10.