N-((Trimethoxysilyl)methyl)aniline

Base Information

• Chemical Name: N-((Trimethoxysilyl)methyl)aniline
• CAS No.: 77855-73-3
• Molecular Formula: C10H17NO3Si
• Molecular Weight: 227.335
• Hs Code.: 2931900090
• European Community (EC) Number: 616-531-1
• DSSTox Substance ID: DTXSID00694862
• Nikkaji Number: J2.211.882J
• Mol file: 77855-73-3.mol

Synonyms:phenylaminomethyl trimethoxysilane

Chemical Property of N-((Trimethoxysilyl)methyl)aniline

Chemical Property:

• Vapor Pressure: 0.011mmHg at 25°C
• Melting Point: -17°C
• Refractive Index: 1.509
• Boiling Point: 262.579 °C at 760 mmHg
• PKA: 4.61±0.50(Predicted)
• Flash Point: 112.604 °C
• PSA: 39.72000
• Density: 1.066 g/cm³
• LogP: 2.00710
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 227.09776994
• Heavy Atom Count: 15
• Complexity: 162

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-((Trimethoxysilyl)methyl)aniline 95+% ^*data from reagent suppliers

Safty Information:

• Statements: 22-48/20/21/22-50/53
• Safety Statements: 26-36/37/39-60

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Si](CNC1=CC=CC=C1)(OC)OC

Technology Process of N-((Trimethoxysilyl)methyl)aniline

There total 3 articles about N-((Trimethoxysilyl)methyl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(chloromethyl)trimethoxysilane (5926-26-1) + aniline (62-53-3) → (N-phenylaminomethyl) trimethoxysilane (77855-73-3)

Guidance literature:

at 85 ℃; for 20h; Inert atmosphere; Sealed tube;

DOI:10.1016/j.jorganchem.2019.120870

Reference yield: 94.0%

→ (N-phenylaminomethyl) trimethoxysilane (77855-73-3)

Guidance literature:

Reference yield: 72.0%

chloromethyltriethoxysilane (15267-95-5) + aniline (62-53-3) → (N-phenylaminomethyl) trimethoxysilane (77855-73-3)

Guidance literature:

chloromethyltriethoxysilane; aniline; at 100 ℃; for 4h;

With ethylenediamine; for 0.166667h;

upstream raw materials:

(chloromethyl)trimethoxysilane

aniline

chloromethyltriethoxysilane

Downstream raw materials:

N-(trimethoxysilylmethyl)acetanilide

Refernces

• 1、 -. "METHOD FOR PRODUCING AMINOORGANOSILANES". Page/Page column 8. . Retrieved 2012/04/04.
• 2、 -. "METHOD FOR THE PRODUCTION OF SILICON COMPOUNDS CARRYING AMINO GROUPS". Page/Page column 15. . Retrieved 2008/06/13.