2,4,6-trifluoroborazine

Base Information

• Chemical Name: 2,4,6-trifluoroborazine
• CAS No.: 13779-24-3
• Molecular Formula: B₃F₃H₃N₃
• Molecular Weight: 134.472
• Mol file: 13779-24-3.mol

Synonyms:B-Trifluoroborazine

Chemical Property of 2,4,6-trifluoroborazine

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 1.16g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,6-trifluoroborazine

There total 4 articles about 2,4,6-trifluoroborazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

B,B',B''-trichloroborazine (933-18-6,26445-82-9) + antimony(III) fluoride (7783-56-4) → 2,4,6-trifluoroborazine (13779-24-3)

Guidance literature:

In toluene; under N2 or Ar; SbF3 and toluene stirred at -78°C; soln. of (HNBCl)3 in toluene added dropwise; warmed to ambient temp.; filtered; filtrate stored at -25°C for 1 d;

DOI:10.1002/ejic.200800169

Reference yield:

ammonia trifluoroborane (13709-86-9) → 2,4,6-trifluoroborazine (13779-24-3)

Guidance literature:

In neat (no solvent); formation of (HNBF)3 on heating NH3BF3 at 140-180 ° C;

Reference yield:

bis(diethylboryl)amine (7397-53-7) → 2,4,6-trifluoroborazine (13779-24-3) + (diethyl)fluoroborane (367-45-3)

Guidance literature:

With BF₃; 0°C, exothermic react.;

DOI:10.1016/S0022-328X(00)89761-2

upstream raw materials:

B,B',B''-trichloroborazine

antimony(III) fluoride

titanium(IV) fluoride

ammonia trifluoroborane

Refernces

• 1、 Jemson, H. M.,Lewis-Bevan, W.,Gerry, M. C. L.. "The infrared spectrum of aminodifluoroborane, NH2BF2: Partial assignment of the fundamentals and analysis of the 21/0 band near 1608 cm-1". . p. 2088 - 2099. Retrieved 2007/10/02.