1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate

Base Information

• Chemical Name: 1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate
• CAS No.: 1435951-96-4
• Molecular Formula: C₁₄H₁₈F₆O₄
• Molecular Weight: 364.285
• Mol file: 1435951-96-4.mol

Synonyms:1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate

Chemical Property of 1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate

There total 2 articles about 1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

D-limonene (5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3) + trifluoroacetic acid (76-05-1) → 1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate (1435951-96-4)

Guidance literature:

With molybdenum(II) trifluoroacetate dimer; In toluene; at 20 - 30 ℃; for 2.5h; regioselective reaction; Inert atmosphere;

DOI:10.1134/S1070363214120196

Reference yield: 51.0%

terpin hydrate (80-53-5,89923-77-3) + trifluoroacetic anhydride (407-25-0) → 1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate (1435951-96-4)

Guidance literature:

In tetrachloromethane; water; at 10 - 20 ℃;

DOI:10.1134/S1070428013040088

Reference yield: 73.0%

1-methyl-1-{4-methyl-4-[(trifluoroacetyl)oxy]cyclohexyl}ethyl trifluoroacetate (1435951-96-4) → terpin hydrate (80-53-5,89923-77-3)

Guidance literature:

With sodium hydroxide; In methanol; water; at 20 - 45 ℃; for 3h;

DOI:10.1134/S1070428013040088

upstream raw materials:

terpin hydrate

trifluoroacetic anhydride

D-limonene

trifluoroacetic acid

Downstream raw materials:

terpin hydrate

Refernces

• 1、 Trishin,Shafeeva,Tamm. "Addition of perfluoroalkanoic acids to (R)-(+)-limonene". . p. 545 - 550. Retrieved 2013/06/27.