2-hexanoyl-4,4'-dimethyldiphenylsulfide

Base Information

• Chemical Name: 2-hexanoyl-4,4'-dimethyldiphenylsulfide
• CAS No.: 137155-98-7
• Molecular Formula: C₂₀H₂₄OS
• Molecular Weight: 312.476
• Mol file: 137155-98-7.mol

Synonyms:2-hexanoyl-4,4'-dimethyldiphenylsulfide

Chemical Property of 2-hexanoyl-4,4'-dimethyldiphenylsulfide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2-hexanoyl-4,4'-dimethyldiphenylsulfide

There total 1 articles about 2-hexanoyl-4,4'-dimethyldiphenylsulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

di-(p-tolyl)sulfane (620-94-0) + Hexanoyl chloride (142-61-0) → 2-hexanoyl-4,4'-dimethyldiphenylsulfide (137155-98-7)

Guidance literature:

With aluminium trichloride; at 5 - 10 ℃; 20-30 min;

DOI:10.1016/S0040-4020(01)96149-6

Reference yield: 95.0%

2-hexanoyl-4,4'-dimethyldiphenylsulfide (137155-98-7) → 2-hexyl-4,4'-dimethyldiphenylsulfide (137156-02-6)

Guidance literature:

With lithium aluminium tetrahydride; aluminium trichloride; In tetrahydrofuran; 1) 25 deg C, 30 min, 2) reflux, 6-12 h;

DOI:10.1016/S0040-4020(01)96149-6

Reference yield:

2-hexanoyl-4,4'-dimethyldiphenylsulfide (137155-98-7) → 2-hexyl-4-methylphenyl-(4-methylphenyl)methylsulfonium fluoroborate

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / LiAlH₄, AlCl₃ / tetrahydrofuran / 1) 25 deg C, 30 min, 2) reflux, 6-12 h

2: 71 percent / CHCl₃ / 10 h / Heating

With lithium aluminium tetrahydride; aluminium trichloride; In tetrahydrofuran; chloroform;

DOI:10.1016/S0040-4020(01)96149-6

upstream raw materials:

di-(p-tolyl)sulfane

Hexanoyl chloride

Downstream raw materials:

2-hexyl-4,4'-dimethyldiphenylsulfide

Refernces