2-(tetraphen-7-yl)cyclohexanol

Base Information

• Chemical Name: 2-(tetraphen-7-yl)cyclohexanol
• CAS No.: 111189-44-7
• Molecular Formula: C₂₄H₂₂O
• Molecular Weight: 326.438
• Mol file: 111189-44-7.mol

Synonyms:2-(7-benzanthryl)cyclohexanol

Chemical Property of 2-(tetraphen-7-yl)cyclohexanol

Chemical Property:

• Vapor Pressure: 1.1E-13mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(tetraphen-7-yl)cyclohexanol

There total 1 articles about 2-(tetraphen-7-yl)cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7-Bromobenz[a]anthracene (32795-84-9) + cyclohexane-1,2-epoxide (286-20-4) → 2-(7-benzanthryl)cyclohexanol (111189-44-7)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) Et₂O, hexane, 2 h, 2.) Et₂O, overnight;

DOI:10.1021/jo00235a005

Reference yield: 85.0%

2-(7-benzanthryl)cyclohexanol (111189-44-7) → 2-(7-benzanthracenyl)cyclohexanone (111189-42-5)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; for 0.5h;

DOI:10.1021/jo00235a005

Reference yield:

2-(7-benzanthryl)cyclohexanol (111189-44-7) → dibenzo[a,e]fluoranthene (5385-75-1) + Benzofluoranthene (203-20-3) + 7-cyclohexenylbenzanthracene (36278-16-7)

Guidance literature:

With PPA; 2,3-dicyano-5,6-dichloro-p-benzoquinone; Yield given. Multistep reaction. Yields of byproduct given; 1.) 110 deg C, 2 h, 2.) benzene, reflux, 30 min;

DOI:10.1021/jo00235a005

upstream raw materials:

7-Bromobenz[a]anthracene

cyclohexane-1,2-epoxide

Downstream raw materials:

dibenzo[a,e]fluoranthene

Benzofluoranthene

7-cyclohexenylbenzanthracene

2-(7-benzanthracenyl)cyclohexanone

Refernces