Technology Process of 1-bromo-4-<2H3>methylthiobenzene
There total 1 articles about 1-bromo-4-<2H3>methylthiobenzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium phosphate; eosin y;
In
methanol;
at 30 ℃;
for 22h;
Glovebox;
Inert atmosphere;
Irradiation;
DOI:10.1021/acs.orglett.0c03562
- Guidance literature:
-
With
potassium ethoxide;
In
ethanol; dimethyl sulfoxide;
at 80 - 140 ℃;
Rate constant;
Kinetics;
Thermodynamic data;
kd, E(act), log A (Arrhenius eq.);
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) Mg / 2.) ether,rt., 1 h
2: 1.) borane-dimethyl sulphide complex 2.) 30percent H2O2 / 1.) THF, 0-5 deg C, 1 h then 20-25 deg C, 3 h 2.) THF, EtOH, water, 25-35 deg C then reflux, 1 h
3: 90 percent / pyridine / benzene / 5 h / Heating
4: 75 percent / LiCl / hexamethylphosphoric acid triamide; H2O / 8 h / 90 °C
With
pyridine; dimethylsulfide borane complex; dihydrogen peroxide; magnesium; lithium chloride;
In
N,N,N,N,N,N-hexamethylphosphoric triamide; water; benzene;
