9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene

Base Information

• Chemical Name: 9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene
• CAS No.: 96913-94-9
• Molecular Formula: C₂₀H₂₆OSi₂
• Molecular Weight: 338.597
• Mol file: 96913-94-9.mol

Synonyms:9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene

Chemical Property of 9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene

There total 1 articles about 9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Ethoxy-1,3-dihydroisobenzofuran (75802-19-6) → 9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene (96913-94-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) diisopropylamine, n-BuLi / 1.) ether, hexane, O deg C, 2 h, 2.) ether, hexane, RT

2: 90 percent / LTMP / diethyl ether; hexane / 14 °C

With n-butyllithium; 2,2,6,6-tetramethylpiperidinyl-lithium; diisopropylamine; In diethyl ether; hexane;

DOI:10.1021/jo00215a031

Reference yield: 100.0%

9,10-bis(trimethylsilyl)-9,10-dihydro-9,10-epoxyanthracene (96913-94-9) → anthracen-9(10H)-one (90-44-8)

Guidance literature:

With trifluoroacetic acid; In chloroform-d1; for 0.0833333h;

DOI:10.1021/jo00358a007

upstream raw materials:

1-Ethoxy-1,3-dihydroisobenzofuran

Downstream raw materials:

anthracen-9(10H)-one

Refernces