3-(2-Bromoethoxy)prop-1-ene

Base Information

• Chemical Name: 3-(2-Bromoethoxy)prop-1-ene
• CAS No.: 15424-04-1
• Molecular Formula: C5H9 Br O
• Molecular Weight: 165.03
• Hs Code.: 2909199090
• European Community (EC) Number: 816-587-9
• DSSTox Substance ID: DTXSID90398948
• Wikidata: Q82201212
• Mol file: 15424-04-1.mol

Synonyms:3-(2-bromoethoxy)prop-1-ene;15424-04-1;3-(2-BROMO-ETHOXY)-PROPENE;2-Allyloxyethyl bromide;1-Propene,3-(2-bromoethoxy)-;3-(2-Bromoethoxy)-propene;allyl bromoethyl ether;3-(2-bromoethoxy)propene;3-(2-Bromoethoxy)-1-propene;SCHEMBL1167419;DTXSID90398948;MFCD06411029;CS-0215137;EN300-226767;A1-00404

Chemical Property of 3-(2-Bromoethoxy)prop-1-ene

Chemical Property:

• Boiling Point: 68.5-69 °C(Press: 36 Torr)
• PSA: 9.23000
• Density: 1.336 g/cm3
• LogP: 1.58390
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 163.98368
• Heavy Atom Count: 7
• Complexity: 45.3

Purity/Quality:

98%min ^*data from raw suppliers

3-(2-bromoethoxy)prop-1-ene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOCCBr

Technology Process of 3-(2-Bromoethoxy)prop-1-ene

There total 5 articles about 3-(2-Bromoethoxy)prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

2-(allyloxy)ethyl 4-methylbenzenesulfonate (50563-72-9) → 2-(allyloxy)ethyl bromide (15424-04-1)

Guidance literature:

With ethylene dibromide; magnesium bromide; In diethyl ether; Ambient temperature;

DOI:10.1246/bcsj.55.1498

Reference yield:

ethylene glycol monoallyl ether (111-45-5,27274-31-3) → 2-(allyloxy)ethyl bromide (15424-04-1)

Guidance literature:

With pyridine; phosphorus tribromide;

DOI:10.1021/ja01275a051

Reference yield:

ethylene glycol (107-21-1) + allyl bromide (106-95-6) → 2-(allyloxy)ethyl bromide (15424-04-1)

Guidance literature:

Multistep reaction; (i) Na, (ii) (PhO)3PBr₂, Py;

DOI:10.1021/ja00493a020

upstream raw materials:

ethylene glycol monoallyl ether

oxirane

allyl bromide

ethylene glycol

Downstream raw materials:

tri-n-butylgermanium bromide

(C₅H₃NC₆H₄OCH₂CH₂OCH₂CHCH₂)2

2-(2-allyloxy-ethoxymethyl)-2-methyl-propane-1,3-diol

(-)-D-1,5-bis-O-allyl-4-O-[2-(allyloxy)ethyl]-2,3,6-tris-O-benzyl-myo-inositol

Refernces

• 1、 Okabe, Masami,Tada, Masaru. "The Reaction of Bis(dimethylglyoximato)(pyridine)cobalt(I), Cobaloxime(I), with 2-(Allyloxy)ethyl Halides and the Photolysis of the Resulting Organo-cobaloximes". . p. 1498 - 1503. Retrieved 2007/10/02.