W(CO)5(1-pentene)

Base Information

• Chemical Name: W(CO)5(1-pentene)
• CAS No.: 53261-74-8
• Molecular Formula: C₁₀H₁₀O₅W
• Molecular Weight: 394.036
• Mol file: 53261-74-8.mol

Synonyms:W(CO)5(1-pentene)

Chemical Property of W(CO)5(1-pentene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of W(CO)5(1-pentene)

There total 2 articles about W(CO)5(1-pentene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

W(CO)5(4-vinylpyridine) (84206-31-5) + 1-penten (109-67-1) → 4-vinylpyridine (100-43-6,329041-72-7) + W(CO)5(1-pentene) (53261-74-8)

Guidance literature:

In further solvent(s); Irradiation (UV/VIS); irrdn. (λ 436 nm) of degassed isopentane soln. of educt contg. 1-pentene; monitored by IR and UV;

DOI:10.1016/S0022-328X(00)96085-6

Reference yield:

trans-[(η(2)-1-pentene)2W(CO)4] (97133-84-1) + carbon monoxide (201230-82-2) + argon → tungsten hexacarbonyl (14040-11-0) + W(CO)5(1-pentene) (53261-74-8) + trans-[W(CO)4(1-pentene)(Ar)] + cis-[(η(2)-1-pentene)2W(CO)4] (97074-03-8)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); Ar-matrix contg. 2% CO; 16 K, 1000 W Hg-Xe lamp, 363 nm, 120 min; reaction partly reversed by irradiation at 445 nm for 20 min; not isolated, detd. by IR spectroscopy; product ratio changing by irradiation at 313 nm;

DOI:10.1016/S0022-328X(96)06725-3

Reference yield:

W(CO)5(1-pentene) (53261-74-8) → W(CO)4(C5H10) (97074-01-6) + 1-penten (109-67-1) + carbon monoxide (201230-82-2)

Guidance literature:

In methyl cyclohexane; Irradiation (UV/VIS); at 77°K; monitored by IR;

upstream raw materials:

W(CO)5(4-vinylpyridine)

1-penten

trans-[(η(2)-1-pentene)2W(CO)4]

carbon monoxide

Downstream raw materials:

W(CO)4(C₅H₁₀)

1-penten

carbon monoxide

Refernces

• 1、 Kelly, John M.,Long, Conor. "GROUP VIA METAL PENTACARBONYL COMPLEXES OF 2- AND 4-VINYLPYRIDINE AND THEIR COPOLYMERS. PREPARATION, SPECTROSCOPIC CHARACTERISATION AND PHOTOCHEMICAL PROPERTIES". . p. 315 - 326. Retrieved 2007/10/02.