(adamantan-2-yl)magnesium bromide

Base Information

• Chemical Name: (adamantan-2-yl)magnesium bromide
• CAS No.: 114332-05-7
• Molecular Formula: C₁₀H₁₅BrMg
• Molecular Weight: 239.438
• Mol file: 114332-05-7.mol

Synonyms:(adamantan-2-yl)magnesium bromide

Chemical Property of (adamantan-2-yl)magnesium bromide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (adamantan-2-yl)magnesium bromide

There total 1 articles about (adamantan-2-yl)magnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

2-adamantyl bromide (7314-85-4) → adamantane (281-23-2) + 2,2'-biadamantane (29542-62-9) + (adamantan-2-yl)magnesium bromide (114332-05-7)

Guidance literature:

With magnesium; ethylene dibromide; In diethyl ether; at 35 ℃; for 10h; Further byproducts given. Title compound not separated from byproducts; no mechanical stirring;

DOI:10.1021/jo00142a023

Reference yield: 80.0%

[(2)H6]acetone (666-52-4) + (adamantan-2-yl)magnesium bromide (114332-05-7) → adamantane (281-23-2) + 1-adamantanol (700-57-2) + 2,2'-biadamantane (29542-62-9) + 2-(2-adamantyl)-2-propanol-d6 (114332-09-1)

Guidance literature:

In diethyl ether; at 0 ℃; for 15h; Further byproducts given. Yields of byproduct given;

Reference yield: 80.0%

[(2)H6]acetone (666-52-4) + (adamantan-2-yl)magnesium bromide (114332-05-7) → adamantane (281-23-2) + 1-adamantanol (700-57-2) + 2,2'-biadamantane (29542-62-9) + adamantane-2-d1 (70334-00-8) + 2-(2-adamantyl)-2-propanol-d6 (114332-09-1)

Guidance literature:

In diethyl ether; at 0 ℃; for 0.25h; Product distribution; without aceton-d₆; several other aldehydes, ketones and acyl chlorides.;

upstream raw materials:

2-adamantyl bromide

Downstream raw materials:

adamantane

1-adamantanol

2,2'-biadamantane

adamantane-2-d₁

Refernces