4-(cyanocarbonyl)-1,2-phenylene diacetate

Base Information

• Chemical Name: 4-(cyanocarbonyl)-1,2-phenylene diacetate
• CAS No.: 2214-15-5
• Molecular Formula: C₁₂H₉NO₅
• Molecular Weight: 247.207
• Mol file: 2214-15-5.mol

Synonyms:4-(cyanocarbonyl)-1,2-phenylene diacetate

Chemical Property of 4-(cyanocarbonyl)-1,2-phenylene diacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(cyanocarbonyl)-1,2-phenylene diacetate

There total 2 articles about 4-(cyanocarbonyl)-1,2-phenylene diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

3,4-(diacetyloxy)benzoyl chloride (57929-25-6) + copper(l) cyanide → 4-(cyanocarbonyl)-1,2-phenylene diacetate (2214-15-5)

Guidance literature:

In acetonitrile; for 4h; Inert atmosphere; Reflux;

DOI:10.1021/acs.orglett.9b03078

Reference yield:

→ 4-(cyanocarbonyl)-1,2-phenylene diacetate (2214-15-5)

Guidance literature:

aus entspr. Benzoylchlorid, CuCN;

Reference yield: 73.0%

4-(cyanocarbonyl)-1,2-phenylene diacetate (2214-15-5) + C31H46O3 → oblongifolin A

Guidance literature:

C₃₁H₄₆O₃; With samarium(III) chloride; triethylamine; In toluene; at 0 ℃; for 0.166667h; Inert atmosphere;

4-(cyanocarbonyl)-1,2-phenylene diacetate; In toluene; at 0 - 20 ℃; for 2h; Inert atmosphere;

With methanol; potassium carbonate; for 2h; Inert atmosphere;

DOI:10.1021/acs.orglett.9b03078

upstream raw materials:

3,4-(diacetyloxy)benzoyl chloride

Downstream raw materials:

(+)-isoxanthochymol

garcinol

Refernces