Technology Process of 4-methyl-1,1':4',1'':4'',1'''-quaterphenyl
There total 8 articles about 4-methyl-1,1':4',1'':4'',1'''-quaterphenyl which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
bis(acetylacetonate)nickel(II); 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazole trafluoroborate;
In
tetrahydrofuran; diethyl ether;
at 25 ℃;
for 1.5h;
Inert atmosphere;
DOI:10.5012/bkcs.2010.31.12.3749
- Guidance literature:
-
With
bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; 1,3-dicyclohexyl-1H-imidazol-3-ium chloride; sodium t-butanolate;
In
toluene;
at 120 ℃;
for 12h;
Glovebox;
Inert atmosphere;
Sealed tube;
DOI:10.1021/ol502583h
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 0.9 g / iodine, Br2 / acetic acid / 1 h / 100 °C / Heating
2: 1.) Mg / 2.) Ni(bpy)Cl2 / THF
With
bromine; iodine; magnesium;
dichloro(2,2'-bipyridine)nickel(II);
In
acetic acid;
DOI:10.1021/j100168a018
