4-Methoxyphenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate

Base Information

• Chemical Name: 4-Methoxyphenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate
• CAS No.: 82200-53-1
• Molecular Formula: C23H26 O6
• Molecular Weight: 398.456
• European Community (EC) Number: 444-080-9,620-344-0
• DSSTox Substance ID: DTXSID101165062
• Nikkaji Number: J642.411B
• Mol file: 82200-53-1.mol

Synonyms:82200-53-1;4-Methoxyphenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate;(4-methoxyphenyl) 4-(6-prop-2-enoyloxyhexoxy)benzoate;4-METHOXYPHENYL 4-{[6-(PROP-2-ENOYLOXY)HEXYL]OXY}BENZOATE;SCHEMBL1958900;DTXSID101165062;C23H26O6;MFCD27979221;AKOS027460701;Benzoesure, 4-[[6-[(1-oxo-2-propenyl)oxy]hexyl]oxy]-, 4-methoxyphenylester;DS-19154;CS-0137240;C76633;A922695;4-Methoxyphenyl4-((6-(acryloyloxy)hexyl)oxy)benzoate;4-Methoxyphenyl 4-[[6-[(1-oxo-2-propen-1-yl)oxy]hexyl]oxy]benzoate

Chemical Property of 4-Methoxyphenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate

Chemical Property:

• Boiling Point: 539.9±45.0 °C(Predicted)
• PSA: 71.06000
• Density: 1.133±0.06 g/cm3(Predicted)
• LogP: 4.58280
• Storage Temp.: 2-8°C
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 14
• Exact Mass: 398.17293854
• Heavy Atom Count: 29
• Complexity: 490

Purity/Quality:

99.9% ^*data from raw suppliers

4-methoxyphenyl4-((6-(acryloyloxy)hexyl)oxy)benzoate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)OC(=O)C2=CC=C(C=C2)OCCCCCCOC(=O)C=C

Technology Process of 4-Methoxyphenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate

There total 5 articles about 4-Methoxyphenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.7%

4-methoxy-phenol (150-76-5) + 4-{[6-(acryloyloxy)hexyl]oxy}benzoic acid (83883-26-5) → 4-(6-acryloyloxyhexyloxy)benzoic acid 4-methoxyphenyl ester (82200-53-1)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 48.5h; Cooling with ice;

DOI:10.1039/d0nj01314e

Reference yield:

1-bromo-6-hexanol (4286-55-9) → 4-(6-acryloyloxyhexyloxy)benzoic acid 4-methoxyphenyl ester (82200-53-1)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium hydroxide / ethanol; water / 36 h / Reflux

2: N,N-dimethyl-aniline / tetrahydrofuran / 48.5 h / 20 °C / Cooling with ice

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 48.5 h / 20 °C / Cooling with ice

With dmap; N,N-dimethyl-aniline; dicyclohexyl-carbodiimide; potassium hydroxide; In tetrahydrofuran; ethanol; dichloromethane; water;

DOI:10.1039/d0nj01314e

Reference yield:

4-(6-hydroxyhexyloxy)benzoic acid (83883-25-4) → 4-(6-acryloyloxyhexyloxy)benzoic acid 4-methoxyphenyl ester (82200-53-1)

Guidance literature:

Multi-step reaction with 2 steps

1: N,N-dimethyl-aniline / tetrahydrofuran / 48.5 h / 20 °C / Cooling with ice

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 48.5 h / 20 °C / Cooling with ice

With dmap; N,N-dimethyl-aniline; dicyclohexyl-carbodiimide; In tetrahydrofuran; dichloromethane;

DOI:10.1039/d0nj01314e

upstream raw materials:

4-hydroxy-benzoic acid

1-bromo-6-hexanol

4-(6-hydroxyhexyloxy)benzoic acid

4-methoxy-phenol

Refernces

• 1、 -. "POLYMERIZABLE COMPOUND AND COMPOSITION CONTAINING THE POLYMERIZABLE COMPOUND". Page/Page column 37-38. . Retrieved 2010/11/28.