(CH₃)3NGeH₃Br

Base Information

• Chemical Name: (CH₃)3NGeH₃Br
• CAS No.: 60342-06-5
• Molecular Formula: C₃H₁₂BrGeN
• Molecular Weight: 214.629
• Mol file: 60342-06-5.mol

Synonyms:(CH₃)3NGeH₃Br

Chemical Property of (CH₃)3NGeH₃Br

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (CH₃)3NGeH₃Br

There total 1 articles about (CH₃)3NGeH₃Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromogermanate (13569-43-2) → germane (7782-65-2) + digermane (13818-89-8) + trigermane (14691-44-2) + (CH3)3NGeH3Br (60342-06-5)

Guidance literature:

With trimethylamine; In neat (no solvent); under N2 or in vac., Me3N : GeH3Br > 1, Me3N condensed onto GeH3Br at -196°C, warmed to -78°C, mixed, then warmed to -63°C; volatile materials removed at -63°C, small quantities of GeH4, Ge2H6 and Ge3H8 (2-8%);

DOI:10.1016/S0020-1693(00)85155-5

Reference yield: 97.8%

(CH3)3NGeH3Br (60342-06-5) → bromogermanate (13569-43-2) + trimethyl ammonium bromide (2840-24-6)

Guidance literature:

With hydrogen bromide; In neat (no solvent); byproducts: germanes; under N2 or in vac., excess HBr, -78°C, 1.0 h;

DOI:10.1016/S0020-1693(00)85155-5

Reference yield: 92.5%

(CH3)3NGeH3Br (60342-06-5) + diborane (19287-45-7) → bromogermanate (13569-43-2) + trimethylamine-borane (75-22-9)

Guidance literature:

In neat (no solvent); byproducts: germanes; under N2 or in vac., excess B2H6, -78°C, 1.0 h;

DOI:10.1016/S0020-1693(00)85155-5

upstream raw materials:

bromogermanate

Downstream raw materials:

bromogermanate

trimethylamine-borane

germane

digermane