3,6-Diphenyl-9H-carbazole

Base Information

• Chemical Name: 3,6-Diphenyl-9H-carbazole
• CAS No.: 56525-79-2
• Molecular Formula: C24H17N
• Molecular Weight: 319.406
• European Community (EC) Number: 805-816-8
• DSSTox Substance ID: DTXSID80985149
• Nikkaji Number: J3.354.639D
• Wikidata: Q82972615
• Mol file: 56525-79-2.mol

Synonyms:3,6-Diphenyl-9H-carbazole;56525-79-2;3,6-diphenylcarbazole;9H-Carbazole, 3,6-diphenyl-;MFCD00222619;6654-68-8;3,6-diphenyl carbazole;3,6-Biphenyl-9H-carbazole;Oprea1_545753;Oprea1_815242;3,6-di-phenyl-9h-carbazole;SCHEMBL149685;3,6-Diphenylcarbazole, 99%;YSZC1788;AMY8728;DTXSID80985149;PCMKGEAHIZDRFL-UHFFFAOYSA-N;STK927806;AKOS002336524;OL10012;SB66927;AC-28755;AS-10598;SY036866;CS-0080917;D4433;FT-0733900;A831073

Chemical Property of 3,6-Diphenyl-9H-carbazole

Chemical Property:

• Vapor Pressure: 1.21E-12mmHg at 25°C
• Melting Point: 186℃
• Refractive Index: 1.722
• Boiling Point: 575.4 °C at 760 mmHg
• PKA: 16.82±0.30(Predicted)
• Flash Point: 255.5 °C
• PSA: 15.79000
• Density: 1.198 g/cm³
• LogP: 6.65510
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 319.136099547
• Heavy Atom Count: 25
• Complexity: 393

Purity/Quality:

99% ^*data from raw suppliers

3,6-Diphenyl-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC3=C(C=C2)NC4=C3C=C(C=C4)C5=CC=CC=C5

Technology Process of 3,6-Diphenyl-9H-carbazole

There total 15 articles about 3,6-Diphenyl-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

3,6-diiodocarbazole (57103-02-3) + phenylboronic acid (98-80-6) → 3,6-diphenylcarbazole (56525-79-2)

Guidance literature:

With barium dihydroxide; tris-(o-tolyl)phosphine; palladium diacetate; In 1,2-dimethoxyethane; water; at 80 ℃; for 8h;

DOI:10.1021/ja021243p

Reference yield: 95.0%

3,6-Diphenyl-9-tosyl-9H-carbazole (1360431-76-0) → 3,6-diphenylcarbazole (56525-79-2)

Guidance literature:

3,6-Diphenyl-9-tosyl-9H-carbazole; With potassium hydroxide; In tetrahydrofuran; water; dimethyl sulfoxide; at 80 ℃; for 4h;

With hydrogenchloride; In tetrahydrofuran; water; dimethyl sulfoxide; at 20 ℃;

DOI:10.1007/s10895-010-0732-z

Reference yield: 94.0%

2,8-diphenyldibenzo[b,d]thiophene 5,5-dioxide → 3,6-diphenylcarbazole (56525-79-2)

Guidance literature:

2,8-diphenyldibenzo[b,d]thiophene 5,5-dioxide; With phenethylamine; lithium hexamethyldisilazane; In 1,4-dioxane; at 100 ℃; for 3h; Schlenk technique; Inert atmosphere;

With potassium hexamethylsilazane; In 1,4-dioxane; at 120 ℃; for 19h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201903916

upstream raw materials:

3,6-diiodocarbazole

phenylboronic acid

3,6-dibromo-9H-carbazole

1,2-dimethoxyethane

Downstream raw materials:

4,4'-bis-[9-(3,6-diphenylcarbazolyl)]-1,1'-biphenyl

bis(4-(3,6-dipenyl-9H-carbazol-9-yl)phenyl)methanone

Refernces

• 1、 -. "Heterocyclic compound and organic electroluminescent device thereof". Paragraph 0125; 0131-0132. . Retrieved 2021/10/05.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0134; 0136-0139. . Retrieved 2020/05/30.