4-(trans-4-Pentylcyclohexyl)phenylboronic acid

Base Information

• Chemical Name: 4-(trans-4-Pentylcyclohexyl)phenylboronic acid
• CAS No.: 143651-26-7
• Molecular Formula: C17H27BO2
• Molecular Weight: 274.211
• Hs Code.: 2931900090
• European Community (EC) Number: 811-156-1
• DSSTox Substance ID: DTXSID70931978
• Nikkaji Number: J1.637.721J
• Mol file: 143651-26-7.mol

Synonyms:143651-26-7;136321-96-5;(4-(trans-4-Pentylcyclohexyl)phenyl)boronic acid;4-(TRANS-4-PENTYLCYCLOHEXYL)PHENYLBORONIC ACID;[4-(4-pentylcyclohexyl)phenyl]boronic acid;4-(TRANS-4-PENTYLCYCLOHEXYL) PHENYL BORONIC ACID;4-(4-pentylcyclohexyl)phenylboronic acid;(4-(4-Pentylcyclohexyl)phenyl)boronic acid;[4-(trans-4-n-Pentylcyclohexyl)phenyl]boronic acid;4-(4-PENTYLCYCLOHEXYL)PHENYLBORONIC ACID, 97per cent;4-(trans-4-pentylcyclohexyl)benzeneboronic acid;[4-(trans-4-pentylcyclohexyl)phenyl]Boronic acid;Boronic acid, B-[4-(4-pentylcyclohexyl)phenyl]-;4-(trans-4-Pentylcyclohexyl)phenylboronic Acid (contains varying amounts of Anhydride);C17H27BO2;4-(4-PENTYLCYCLOHEXYL)PHENYLBORONIC ACID, 97%;Boronic acid, [4-(trans-4-pentylcyclohexyl)phenyl]-;SCHEMBL2554148;SCHEMBL6558025;DTXSID70931978;JFESOTHKCUMHGA-SHTZXODSSA-N;AMY18526;MFCD09750938;STK061666;AKOS005146052;AKOS005388075;SB66558;DS-13540;CS-0035191;FT-0659970;FT-0690093;P2363;4-trans(4-n-Pentylcyclohexyl)phenylboronicacid;D70453;[4-(Trans-4-Pentylcyclohexyl)phenyl]boronicacid;A807062;4-(trans-4-Pentylcyclohexyl)phenylboronic Acid, >/=95%;[4-(4beta-Pentylcyclohexane-1alpha-yl)phenyl]boronic acid

Chemical Property of 4-(trans-4-Pentylcyclohexyl)phenylboronic acid

Chemical Property:

• Vapor Pressure: 7.65E-08mmHg at 25°C
• Refractive Index: 1.521
• Boiling Point: 421.073 °C at 760 mmHg
• Flash Point: 208.458 °C
• PSA: 40.46000
• Density: 1.018 g/cm³
• LogP: 3.22050
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 274.2104103
• Heavy Atom Count: 20
• Complexity: 254

Purity/Quality:

99% ^*data from raw suppliers

(4-(trans-4-Pentylcyclohexyl)phenyl)boronicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=CC=C(C=C1)C2CCC(CC2)CCCCC)(O)O

Technology Process of 4-(trans-4-Pentylcyclohexyl)phenylboronic acid

There total 2 articles about 4-(trans-4-Pentylcyclohexyl)phenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Trimethyl borate (121-43-7,63156-11-6) + 1-bromo-4-(trans-4-pentylcyclohexyl)benzene (79832-89-6,153873-83-7) → 4-(trans-4-pentylcyclohexyl)phenylboronic acid (143651-26-7)

Guidance literature:

1-bromo-4-(trans-4-pentylcyclohexyl)benzene; With magnesium; In tetrahydrofuran; at 20 ℃; for 3h;

Trimethyl borate; In tetrahydrofuran; at 20 - 78 ℃; for 24h;

DOI:10.1021/ma500515s

Reference yield: 52.0%

1-bromo-4-(trans-4-pentylcyclohexyl)benzene (79832-89-6,153873-83-7) → 4-(trans-4-pentylcyclohexyl)phenylboronic acid (143651-26-7)

Guidance literature:

1-bromo-4-(trans-4-pentylcyclohexyl)benzene; With magnesium; In tetrahydrofuran; at 20 ℃; for 2h;

With Trimethyl borate; In tetrahydrofuran; at 20 ℃; for 5h; Further stages.;

DOI:10.1021/ja070701x

Reference yield: 96.0%

4-(trans-4-pentylcyclohexyl)phenylboronic acid (143651-26-7) + C78H108Br2O4 → C112H158O4

Guidance literature:

With aq. NaCO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; Heating;

DOI:10.1021/ja070701x

upstream raw materials:

1-bromo-4-(trans-4-pentylcyclohexyl)benzene

Trimethyl borate

Downstream raw materials:

4'-(trans-4-pentylcyclohexyl)-[1,1‘-biphenyl]-4-ol

Refernces

• 1、 Goh, Munju,Kyotani, Mutsumasa,Akagi, Kazuo. "Highly twisted helical polyacetylene with morphology free from the bundle of fibrils synthesized in chiral nematic liquid crystal reaction field". . p. 8519 - 8527. Retrieved 2008/02/09.