PERCHLORATE

Base Information

• Chemical Name: PERCHLORATE
• CAS No.: 1059018-91-5
• Molecular Formula: ClO₄
• Molecular Weight: 99.4506
• Mol file: 1059018-91-5.mol

Synonyms:

Chemical Property of PERCHLORATE

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

PERCHLORATE STANDARD 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Description: Perchlorate has been known to inhibit the transport of iodide into the thyroid gland, and it has been clinically used for the treatment of thyrotoxicosis since the 1950s. Industrially, perchlorate has been produced in large amounts for rocket fuels and military applications.It was discovered in the 1990s that perchlorate remains unreacted in environments such as soil, plants, and animals located in or near many military installations and rocket manufacturing facilities, at potentially thyroiddisrupting levels.
• Physical properties: Colorless, no odor, and stable at room or normal temperature. Perchlorates are soluble in water (249 g/L for ammonium perchlorate), and do not volatilize from soil or water surfaces.

Technology Process of PERCHLORATE

There total 30 articles about PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Sn(tetra-p-tolylporphyrin)(ClO4)2 (122380-54-5) → Sn(tetra-p-tolylporphyrin)(ClO4)(tetrahydrofuran)(1+) + perchlorate(1-) (14797-73-0,1059018-91-5)

Guidance literature:

With THF; In tetrahydrofuran;

DOI:10.1039/DT9890001531

Reference yield:

ammonium chloride → nitrogen trichloride (10025-85-1) + perchlorate(1-) (14797-73-0,1059018-91-5)

Guidance literature:

In water; Electrolysis;

Reference yield:

chlorate (14866-68-3,80434-34-0) → chlorine dioxide (10049-04-4,25052-55-5) + chloride (16887-00-6) + oxygen (80937-33-3) + perchlorate(1-) (14797-73-0,1059018-91-5) + chlorine (7782-50-5)

Guidance literature:

With dihydrogen peroxide; In water; acidic soln.;;

upstream raw materials:

perchloric acid

chloride

Nitrate

nitric acid

Downstream raw materials:

{Os(PCH₃IC₆H₅)Cl(CO)2(P(C₆H₅)3)2}⁽¹⁺⁾*ClO₄^(1-)={Os(PCH₃IC₆H₅)Cl(CO)2(P(C₆H₅)3)2}ClO₄

[1,4-bis(diphenylphosphino)butane-P,P'](N,N'-diethyldithiocarbamato-S,S')nickel(II) perchlorate

[Pt(CHC6H5CH2NEt2-κC,κN)(N,N,N',N'-tetramethylethylenediamine)]ClO4

[Ru(1,10-phenanthroline)2(6-p-anisyl-2-(p-anisylamino)-3(4H)-p-anisylimine-9-methoxyphenazine(-H))]ClO₄

Refernces

• 1、 Fowler, G. J.,Grant, J.. "". . p. 272 - 282. Retrieved 1890.
• 2、 Krack,Van Eldik. "Temperature and pressure effects on the outer-sphere electron-transfer reaction between hexacyanoferrate(II) and pentaamminecobalt(III) complexes in aqueous solution. Comparison of experimental and theoretical volumes of activation". . p. 1700 - 1704. Retrieved 2008/10/08.
• 3、 Alekseev, V. I.,Zyubina, T. S.,Zyubin, A. S.,Baluev, A. V.. "MASS-SPECTROMETRIC AND QUANTUM-CHEMICAL INVESTIGATION OF THERMOCHEMICAL CHARACTERISTICS OF CHLORINE OXIDES". . p. 2092 - 2096. Retrieved 2007/10/02.