hexaazatriphenylenehexacarboxylic acid trianhydride

Base Information

• Chemical Name: hexaazatriphenylenehexacarboxylic acid trianhydride
• CAS No.: 105618-29-9
• Molecular Formula: C₁₈N₆O₉
• Molecular Weight: 444.233
• Mol file: 105618-29-9.mol

Synonyms:

Chemical Property of hexaazatriphenylenehexacarboxylic acid trianhydride

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexaazatriphenylenehexacarboxylic acid trianhydride

There total 4 articles about hexaazatriphenylenehexacarboxylic acid trianhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

hexaazatriphenylenehexacarboxylic acid (105598-29-6) → hexaazatriphenylenehexacarboxylic acid trianhydride (105618-29-9)

Guidance literature:

With acetic anhydride; at 115 ℃; for 0.166667h;

DOI:10.1021/jo00376a036

Reference yield:

hexaketocyclohexane (527-31-1) → hexaazatriphenylenehexacarboxylic acid trianhydride (105618-29-9)

Guidance literature:

Multi-step reaction with 4 steps

1.1: acetic acid / 2 h / Reflux

2.1: sulfuric acid / 72 h / 20 °C

3.1: acetic acid; sodium nitrite; trifluoroacetic acid / 12 h

3.2: 12 h / 20 °C

4.1: acetic anhydride / 0.33 h / 115 - 117 °C / Inert atmosphere

With sulfuric acid; acetic anhydride; acetic acid; trifluoroacetic acid; sodium nitrite;

DOI:10.1039/c8nj03793k

Reference yield:

dipyrazino[2,3-f:20,30-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile (105598-27-4) → hexaazatriphenylenehexacarboxylic acid trianhydride (105618-29-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sulfuric acid / 72 h / 20 °C

2.1: acetic acid; sodium nitrite; trifluoroacetic acid / 12 h

2.2: 12 h / 20 °C

3.1: acetic anhydride / 0.33 h / 115 - 117 °C / Inert atmosphere

With sulfuric acid; acetic anhydride; acetic acid; trifluoroacetic acid; sodium nitrite;

DOI:10.1039/c8nj03793k

upstream raw materials:

hexaazatriphenylenehexacarboxylic acid

hexaketocyclohexane

dipyrazino[2,3-f:20,30-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile

2,3,6,7,10,11-hexaamide-1,4,5,8,9,12-hexa azatriphenylene

Downstream raw materials:

3,7,11-Tris-pentafluorophenylcarbamoyl-1,4,5,8,9,12-hexaaza-triphenylene-2,6,10-tricarboxylic acid

Refernces

• 1、 Kanakarajan, K.,Czarnik, Anthony W.. "Syntheses of Some Hexacarboxylic Acid Derivatives of Hexaazatriphenylene". . p. 1869 - 1872. Retrieved 2007/10/02.