Tri-tert-butylborane

Base Information

• Chemical Name: Tri-tert-butylborane
• CAS No.: 1113-42-4
• Molecular Formula: C12H27B
• Molecular Weight: 182.157
• DSSTox Substance ID: DTXSID90507871
• Nikkaji Number: J1.757.563E
• Wikidata: Q82364399
• Mol file: 1113-42-4.mol

Synonyms:1113-42-4;tri-tert-butylborane;tri-t-butylborane;Tris(tert-butyl)-boron;DTXSID90507871

Chemical Property of Tri-tert-butylborane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 182.2205810
• Heavy Atom Count: 13
• Complexity: 128

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C(C)(C)C)(C(C)(C)C)C(C)(C)C

Technology Process of Tri-tert-butylborane

There total 3 articles about Tri-tert-butylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isobutene (115-11-7,15220-85-6) + diborane (19287-45-7) → triisobutylborane (1116-39-8) + tri-tert-butylborane (1113-42-4)

Guidance literature:

at 100°C 22 h or room temp.;

DOI:10.1021/ja01186a020

Reference yield:

isobutene (115-11-7,15220-85-6) → triisobutylborane (1116-39-8) + tri-tert-butylborane (1113-42-4)

Guidance literature:

bei Raumtemperatur im Rohr;

DOI:10.1021/ja01186a020

Reference yield:

triethylamine-borane (1722-26-5) + isobutene (115-11-7,15220-85-6) → tri-tert-butylborane (1113-42-4) + triethylamine (121-44-8)

Guidance literature:

In neat (no solvent); heating to 200°C in an autoclave;;

DOI:10.1021/ja01527a010

upstream raw materials:

isobutene

diborane

triethylamine-borane

Downstream raw materials:

t-butylboronic acid