Trimethyl(phenoxy)stannane

Base Information

• Chemical Name: Trimethyl(phenoxy)stannane
• CAS No.: 1529-50-6
• Molecular Formula: C9H14OSn
• Molecular Weight: 256.92
• DSSTox Substance ID: DTXSID00587043
• Wikidata: Q82479290
• Mol file: 1529-50-6.mol

Synonyms:Trimethyl(phenoxy)stannane;trimethyltin phenolate;1529-50-6;DTXSID00587043

Chemical Property of Trimethyl(phenoxy)stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 258.006668
• Heavy Atom Count: 11
• Complexity: 111

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)OC1=CC=CC=C1

Technology Process of Trimethyl(phenoxy)stannane

There total 5 articles about Trimethyl(phenoxy)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium phenoxide (139-02-6) + trimethyltin bromide (1066-44-0) → trimethylphenoxystannane (1529-50-6)

Guidance literature:

With ammonia;

Reference yield:

1-phenoxy-2-propyne (13610-02-1) + hexamethyldistannane (661-69-8) → allenyltrimethylstannane (4104-88-5) + trimethylphenoxystannane (1529-50-6)

Guidance literature:

In neat (no solvent); at temp. above 80°C;

DOI:10.1016/S0022-328X(00)99691-8

Reference yield:

trimethylstannane (1631-73-8) + Triethyltinphenolate (1529-30-2) → triethylstannane (997-50-2) + trimethylphenoxystannane (1529-50-6)

Guidance literature:

In further solvent(s); equilibrium in azoisobutyric acid dinitrile at 40°C; examination with NMR-spectroscopy;;

upstream raw materials:

sodium phenoxide

trimethyltin bromide

trimethylstannane

Triethyltinphenolate

Downstream raw materials:

(benzyloxy)benzene

trimethyltin bromide

2-phenoxy-1-propanol

sodium phenoxide

Refernces

• 1、 Mitchell, T. N.,Amamria, A.,Killing, H.,Rutschow, D.. "SYNTHESIS OF (Z)-1,2-BIS(TRIMETHYLSTANNYL)-1-ALKENES BY PLATINUM-CATALYSED ADDITION OF HEXAMETHYLDISTANNANE TO 1-ALKYNES". . p. C45 - C47. Retrieved 2007/10/02.