Butylamine hydrobromide

Base Information

• Chemical Name: Butylamine hydrobromide
• CAS No.: 15567-09-6
• Molecular Formula: C4H11N.BrH
• Molecular Weight: 154.05
• European Community (EC) Number: 811-785-1
• DSSTox Substance ID: DTXSID80480109
• Mol file: 15567-09-6.mol

Synonyms:butylamine hydrobromide;15567-09-6;1-Butanamine, hydrobromide;butan-1-amine;hydrobromide;1-Butanamine, hydrobromide (1:1);n-butylammonium bromide;butylammonium bromide;butylaminehydrobromide;BUTYLAMINE HBR;butan-1-amine hydrobromide;DTXSID80480109;n-Butylammonium bromide, >=98%;MFCD01874353;AKOS024272194;AS-60914;B5186;T70340

Chemical Property of Butylamine hydrobromide

Chemical Property:

• Melting Point: 205.4 °C
• PSA: 26.02000
• LogP: 2.40360
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 153.01531
• Heavy Atom Count: 6
• Complexity: 13.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Butylamine Hydrobromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN.Br
• Description: N-Butylammonium bromide (BABr) is commonly used to tune colloidal perovskite nanoplatelet structures for desired absorption/emission energy and device performance?for perovskite LEDs and Solar cells.
• Uses: Organohalide based perovskites have emerged as an important class of material for solar cell applications. Our perovskites precursors are useful for synthesizing mixed cation or anion perovskites needed for the optimization of the band gap, carrier diffusion length and power conversion efficiency of perovskites based solar cells.

Technology Process of Butylamine hydrobromide

There total 13 articles about Butylamine hydrobromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

BrH*C12H17NO2 → N-butylammonium bromide (15567-09-6)

Guidance literature:

In water; pH=5.6 - 7.4; pH-value; Irradiation;

DOI:10.1021/acs.joc.5b01770

Reference yield: 85.0%

2-(β,β-dibromovinyl)-5-nitrofuran (63708-87-2) + N-butylamine (109-73-9,85404-21-3) → N-butylammonium bromide (15567-09-6) + N,N-dibutyl-5-nitrofurylacetamidine

Guidance literature:

In acetonitrile; overnight;

Reference yield: 68.0%

((C4H9)NH2)6NiBr2 (30994-42-4) + N-butylamine (109-73-9,85404-21-3) → N,N'-di-n-butylurea (1792-17-2) + N,N'-bis(n-butyl)oxamide (14040-75-6) + N-butylammonium bromide (15567-09-6) + tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; diethyl ether; addn. of RNH2 to suspn. of complex, CO (40 bar), warmed up to 45°C, 20h, hydrolysis with H2SO4, sepn. of organic phase, dried, crystn. of organic products from hexane/CHCl3 = 20/1;

DOI:10.1016/S0022-328X(00)99113-7

upstream raw materials:

benzyl bromide

N-butylamine

3-bromo-1-phenylpropan-1-one

meta-bromobenzyl bromide

Downstream raw materials:

N-cyclohexylidenebutylamine

3-bromo-N-(1-(4-fluorophenyl)ethylidene)propan-1-amine

3-bromo-N,N’-bis(trimethylsilyl)propan-1-amine

Bu₄N[Au(C₆F₅)(2,4,6-C₆F₃H₂)I₂]

Refernces

• 1、 Ni, Mengfei,Guan, Yangfan,Wu, Lin,Deng, Chao,Hu, Xiaoyu,Jiang, Juli,Lin, Chen,Wang, Leyong. "Improved recognition of alkylammonium salts by ion pair recognition based on a novel heteroditopic pillar[5]arene receptor". . p. 6409 - 6413. Retrieved 2012.
• 2、 Ji, Chengmin,Luo, Junhua,Yao, Yunpeng,Zhang, Xinyuan,Zhu, Tingting. "In Situ Epitaxial Growth of Centimeter-Sized Lead-Free (BA)2CsAgBiBr7/Cs2AgBiBr6Heterocrystals for Self-Driven X-ray Detection". supporting information. p. 20802 - 20810. Retrieved 2021/12/14.