1,2-Epoxytridecane

Base Information

• Chemical Name: 1,2-Epoxytridecane
• CAS No.: 1713-31-1
• Molecular Formula: C₁₃H₂₆O
• Molecular Weight: 198.349
• Mol file: 1713-31-1.mol

Synonyms:1,2-epoxytridecane;2-undecyloxirane;Undecyl-oxiran;undecyl-oxirane;

Chemical Property of 1,2-Epoxytridecane

Chemical Property:

• PSA: 12.53000
• LogP: 4.30610

Purity/Quality:

95% ^*data from raw suppliers

2-Undecyloxirane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Epoxytridecane

There total 50 articles about 1,2-Epoxytridecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-tridecene (2437-56-1) → (+/-)-1,2-epoxytridecane (1713-31-1,59812-92-9,59829-81-1,59829-82-2)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -2 - 27 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c6ob01597b

Reference yield: 95.0%

(carboxymethyl)methylphenylsulfonium trifluoromethanesulfonate + Dodecanal (112-54-9) → (+/-)-1,2-epoxytridecane (1713-31-1,59812-92-9,59829-81-1,59829-82-2)

Guidance literature:

With caesium carbonate; In tetrahydrofuran; at 80 ℃; for 12h;

DOI:10.1016/j.tet.2008.10.019

Reference yield: 94.0%

Dodecanal (112-54-9) + trimethylsulfoxonium iodide (1774-47-6) → (+/-)-1,2-epoxytridecane (1713-31-1,59812-92-9,59829-81-1,59829-82-2)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; at 20 - 60 ℃;

DOI:10.1081/SCC-120021041

upstream raw materials:

Perbenzoic acid

1-tridecene

1,2-tridecanediol

Dodecanal

Downstream raw materials:

(S)-3-tetradecanol

tridecanal

(S)-(+)-tridecan-2-ol

(S)-3-Hydroxy-tetradecanenitrile

Refernces

• 1、 Coke,J.L.,Richon,A.B.. "-". . p. 3516 - 3517. Retrieved 1976.
• 2、 Ciaccio, James A.,Drahus, Antoinette L.,Meis, Regina M.,Tingle, Carice T.,Smrtka, Michael,Geneste, Richard. ""Instant methylide" modification of the Corey-Chaykovsky epoxide synthesis". . p. 2135 - 2143. Retrieved 2003.
• 3、 Kim, Soohyung,Jeong, Ha Young,Kim, Seonghan,Kim, Hongsik,Lee, Sojeong,Cho, Jaeheung,Kim, Cheal,Lee, Dongwhan. "Proton Switch in the Secondary Coordination Sphere to Control Catalytic Events at the Metal Center: Biomimetic Oxo Transfer Chemistry of Nickel Amidate Complex". supporting information. p. 4700 - 4708. Retrieved 2021/02/12.
• 4、 Jeong, Ah Rim,Shin, Jong Won,Jeong, Jong Hwa,Bok, Kwon Hee,Kim, Cheal,Jeong, Donghyun,Cho, Jaeheung,Hayami, Shinya,Min, Kil Sik. "Dinuclear Iron(III) and Nickel(II) Complexes Containing N-(2-Pyridylmethyl)-N′-(2-hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties". . p. 3023 - 3033. Retrieved 2017/03/13.